ICCAS OpenIR
Synthesis and characterization of a novel oligosiloxane containing alternative ladderlike structure via charge-transfer interaction
Yuan, Q; Ji, SX; Zhang, RB; He, CB; Chung, NT
2001-06-01
Source PublicationPOLYMER INTERNATIONAL
ISSN0959-8103
Volume50Issue:6Pages:643-650
AbstractA novel oligosiloxane containing alternative ladderlike structure involving viologen groups has been prepared via donor-acceptor interaction-assisted template polymerization. The monomer used as the electron-donor component, N,N ' -bis (3-methyldimethoxyl-silylpropyl) -4,4 ' -bipyridinium dihexafluorophosphate and its precursor, N,N ' -bis(3-methyldimethoxyl-silylpropyl) -4,4 ' -bipyridinium dibromide were first synthesized successfully in high yield. This oligosiloxane, which displays interesting elect ochromic properties, has been characterized by FTIR, W-vis, (HNMR)-H-1, (SiNMR)-Si-29, X-ray diffraction (XRD), and vapour pressure osmometry (VPO). (C) 2001 Society of Chemical Industry.
KeywordOligosiloxane Charge-transfer Interaction
Indexed BySCI
Language英语
WOS IDWOS:000169066300003
PublisherWILEY-BLACKWELL
Citation statistics
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/77664
Collection中国科学院化学研究所
Corresponding AuthorZhang, RB
Affiliation1.Chinese Acad Sci, Inst Chem, Ctr Mol Sci, PCLCC,Polymer Chem Lab, Beijing 100080, Peoples R China
2.Chinese Acad Sci, China Petro Chem Corp Ctr, Ctr Mol Sci, Inst Chem, Beijing 100080, Peoples R China
3.Natl Univ Singapore, Inst Mat Res & Engn, Singapore 117548, Singapore
Recommended Citation
GB/T 7714
Yuan, Q,Ji, SX,Zhang, RB,et al. Synthesis and characterization of a novel oligosiloxane containing alternative ladderlike structure via charge-transfer interaction[J]. POLYMER INTERNATIONAL,2001,50(6):643-650.
APA Yuan, Q,Ji, SX,Zhang, RB,He, CB,&Chung, NT.(2001).Synthesis and characterization of a novel oligosiloxane containing alternative ladderlike structure via charge-transfer interaction.POLYMER INTERNATIONAL,50(6),643-650.
MLA Yuan, Q,et al."Synthesis and characterization of a novel oligosiloxane containing alternative ladderlike structure via charge-transfer interaction".POLYMER INTERNATIONAL 50.6(2001):643-650.
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