ICCAS OpenIR
Quantitative determination of the contribution of charge-transfer complex in the microemulsion copolymerization of N-butyl maleimide and styrene
Zhao, YL; Liu, PS; Liu, HW; Jiang, J; Chen, CF; Xi, F
2001-06-15
Source PublicationMACROMOLECULAR RAPID COMMUNICATIONS
ISSN1022-1336
Volume22Issue:8Pages:633-637
AbstractBy using sodium dodecyl sulfate (SDS) and pentanol (PTL) as emulsifiers, the oil-in-water microemulsion containing N-butyl maleimide (NBMI, M-1) and styrene (St, M-2) was prepared. The microemulsion copolymerization using potassium persulfate (KPS) as an initiator was investigated. On the basis of kinetic model proposed by SHAN Guo-Rong, the reactivity ratios of free monomers and the charge-transfer complex (CTC) in the copolymerization were found to be r(12) = 0.0420 r(21) = 0.0644 r(1C) = 0.00576 and r(2C) = 0.00785, respectively. A kinetic treatment based on this model was used to quantitatively estimate the contribution of CTC to the total copolymerization rate in the NBMI/St copolymerization It was about 17.0 - 20.0% for a wide range of monomer feed ratios.
Indexed BySCI
Language英语
WOS IDWOS:000169627200016
PublisherWILEY-V C H VERLAG GMBH
Citation statistics
Cited Times:11[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/77620
Collection中国科学院化学研究所
Corresponding AuthorXi, F
Affiliation1.Chinese Acad Sci, Inst Chem, Ctr Mol Sci, State Key Lab Polymer Phys, Beijing 100080, Peoples R China
2.Xiangtan Univ, Coll Chem & Chem Engn, Xiangtan 411105, Peoples R China
Recommended Citation
GB/T 7714
Zhao, YL,Liu, PS,Liu, HW,et al. Quantitative determination of the contribution of charge-transfer complex in the microemulsion copolymerization of N-butyl maleimide and styrene[J]. MACROMOLECULAR RAPID COMMUNICATIONS,2001,22(8):633-637.
APA Zhao, YL,Liu, PS,Liu, HW,Jiang, J,Chen, CF,&Xi, F.(2001).Quantitative determination of the contribution of charge-transfer complex in the microemulsion copolymerization of N-butyl maleimide and styrene.MACROMOLECULAR RAPID COMMUNICATIONS,22(8),633-637.
MLA Zhao, YL,et al."Quantitative determination of the contribution of charge-transfer complex in the microemulsion copolymerization of N-butyl maleimide and styrene".MACROMOLECULAR RAPID COMMUNICATIONS 22.8(2001):633-637.
Files in This Item:
There are no files associated with this item.
Related Services
Recommend this item
Bookmark
Usage statistics
Export to Endnote
Google Scholar
Similar articles in Google Scholar
[Zhao, YL]'s Articles
[Liu, PS]'s Articles
[Liu, HW]'s Articles
Baidu academic
Similar articles in Baidu academic
[Zhao, YL]'s Articles
[Liu, PS]'s Articles
[Liu, HW]'s Articles
Bing Scholar
Similar articles in Bing Scholar
[Zhao, YL]'s Articles
[Liu, PS]'s Articles
[Liu, HW]'s Articles
Terms of Use
No data!
Social Bookmark/Share
All comments (0)
No comment.
 

Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.