ICCAS OpenIR
Monte Carlo simulation of phase behavior of polymer blends with special interactions
Jiang, W; Shi, TF; Jiang, SC; An, LJ; Yan, DH; Jiang, BZ
2001-10-17
Source PublicationMACROMOLECULAR THEORY AND SIMULATIONS
ISSN1022-1344
Volume10Issue:8Pages:750-755
AbstractFull Paper: The phase, behavior of A-B-random copolymer/C-homopolymer, blends with special interaction was studied by a. Monte, Carlo simulation in two dimensions. The interaction between I segment A and segment C was repulsive, whereas it was attractive between segment B and segment C. The simulation results showed that the blend became two large co-continuous phase domains at lower segment-B component compositions, indicating that the blend showed spinodal decomposition. With an increase of the segment-B component, the miscibility between the copolymer,and the polymer was gradually improved up to being miscible. In addition, it was found that segment B tended to move to the surface of the copolymer phase in the case of a lower component of segment B. On the other hand, if was observed that the average, end-to-end distances ((h) over bar) for both copolymer and polymer changed slowly with increasing segment-B component of the copolymer up to 40%, thereafter they increased considerably with increasing segment B component. Moreover, it was found that the (h) over bar of the copolymer was obviously shorter than that of the homopolymer for the segment-B composition, region from 0% to 80%. Finally, a, phase diagram showing I phase and - II phase regions under the condition of constant-temperature is presented.
Indexed BySCI
Language英语
WOS IDWOS:000171981600002
PublisherWILEY-V C H VERLAG GMBH
Citation statistics
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/77402
Collection中国科学院化学研究所
Corresponding AuthorJiang, W
AffiliationChinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China
Recommended Citation
GB/T 7714
Jiang, W,Shi, TF,Jiang, SC,et al. Monte Carlo simulation of phase behavior of polymer blends with special interactions[J]. MACROMOLECULAR THEORY AND SIMULATIONS,2001,10(8):750-755.
APA Jiang, W,Shi, TF,Jiang, SC,An, LJ,Yan, DH,&Jiang, BZ.(2001).Monte Carlo simulation of phase behavior of polymer blends with special interactions.MACROMOLECULAR THEORY AND SIMULATIONS,10(8),750-755.
MLA Jiang, W,et al."Monte Carlo simulation of phase behavior of polymer blends with special interactions".MACROMOLECULAR THEORY AND SIMULATIONS 10.8(2001):750-755.
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