ICCAS OpenIR
Coordination induced monolayer formation and fabrication of a novel conductive Langmuir-Schaefer film of benzimidazole-containing Schiff bases without a substituted alkyl chain
Cai, JF; Liu, MH; Yu, G; Liu, YQ
2001
Source PublicationJOURNAL OF MATERIALS CHEMISTRY
ISSN0959-9428
Volume11Issue:7Pages:1924-1927
AbstractTwo benzimidazole-containing Schiff bases: 2-[(2'-hydroxybenzylidene)amino]benzimidazole (HBA) and 2-[(2'-hydroxynaphthylmethylidene)amino]benzimidazole (HNA), which have no substituted long alkyl chain, have been found to form stable monolayers at the air-water interface when Ag(I) ions are present in the subphase. The monolayers can be further transferred onto solid substrates using the horizontal lifting method. The transferred films were characterized by UV-Vis absorption, X-ray photoelectron spectra (XPS) and X-ray diffraction. It has been found that monolayers were formed through the coordination between the benzimidazole moiety and Ag(I) ions. The transferred Langmuir-Schaefer (LS) films thus formed showed a relatively large conductivity in the order of 10(-1) S cm(-1). In addition, photoirradiation upon the film can cause a change in the conductivity.
Indexed BySCI
Language英语
WOS IDWOS:000169554200031
PublisherROYAL SOC CHEMISTRY
Citation statistics
Cited Times:5[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/77222
Collection中国科学院化学研究所
Corresponding AuthorLiu, MH
Affiliation1.Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Lab Colloid & Interface Sci, Beijing 100080, Peoples R China
2.Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Lab Organ Solids, Beijing 100080, Peoples R China
Recommended Citation
GB/T 7714
Cai, JF,Liu, MH,Yu, G,et al. Coordination induced monolayer formation and fabrication of a novel conductive Langmuir-Schaefer film of benzimidazole-containing Schiff bases without a substituted alkyl chain[J]. JOURNAL OF MATERIALS CHEMISTRY,2001,11(7):1924-1927.
APA Cai, JF,Liu, MH,Yu, G,&Liu, YQ.(2001).Coordination induced monolayer formation and fabrication of a novel conductive Langmuir-Schaefer film of benzimidazole-containing Schiff bases without a substituted alkyl chain.JOURNAL OF MATERIALS CHEMISTRY,11(7),1924-1927.
MLA Cai, JF,et al."Coordination induced monolayer formation and fabrication of a novel conductive Langmuir-Schaefer film of benzimidazole-containing Schiff bases without a substituted alkyl chain".JOURNAL OF MATERIALS CHEMISTRY 11.7(2001):1924-1927.
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