ICCAS OpenIR
Preparation of poly (styrene-co-4-vinyl pyridine) /silica nanoscale hybrids supported cyclopentadienyltitanium trichloride (CpTiCl3) catalyst and styrene polymerization
Zhu, N; Tang, T; Cui, DM; Feng, ZL; Huang, BT
2001-12-01
Source PublicationCHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE
ISSN0251-0790
Volume22Issue:12Pages:2117-2119
AbstractTo obtain a novel support with practical value for metallocene catalyst (eta -C5H5)TiCl3 (CpTiCl3), poly (styrene-co-4-vinylpyridine) /SiO2 nanoscale hybrid material (SrP/SiO2) was firstly produced as support. After pretreatment by methylaluminoxane (MAO), the hybrid materials reacted with CpTiCl3. The results from SAXS, SEM and TEM indicated the morphology and structure of organic/inorganic hybrid materials, and the size of inorganic particle in hybrid was nanoscale. The results from IR and XPS showed that there were two possible cationic active species in the hybrid-supported catalyst, the polymerization results of styrene proved this possibility.
Keyword(Stryrene-4-vinylpyridine) Copolymer Organic-inorganic Hybrids Cyclopentadienyltitanium Trichloride Support
Indexed BySCI
Language英语
WOS IDWOS:000172815300042
PublisherHIGHER EDUCATION PRESS
Citation statistics
Cited Times:1[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/77182
Collection中国科学院化学研究所
Corresponding AuthorTang, T
Affiliation1.Chinese Acad Sci, Changchun Inst Appl Chem, Polymer Chem United Lab, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China
2.Chinese Acad Sci, China Petro Chem Corp, Changchun 130022, Peoples R China
3.NE Univ Technol, Dept Chem, Shenyang 110006, Peoples R China
4.Jilin Inst Technol, Dept Chem Engn, Changchun 130012, Peoples R China
Recommended Citation
GB/T 7714
Zhu, N,Tang, T,Cui, DM,et al. Preparation of poly (styrene-co-4-vinyl pyridine) /silica nanoscale hybrids supported cyclopentadienyltitanium trichloride (CpTiCl3) catalyst and styrene polymerization[J]. CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,2001,22(12):2117-2119.
APA Zhu, N,Tang, T,Cui, DM,Feng, ZL,&Huang, BT.(2001).Preparation of poly (styrene-co-4-vinyl pyridine) /silica nanoscale hybrids supported cyclopentadienyltitanium trichloride (CpTiCl3) catalyst and styrene polymerization.CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,22(12),2117-2119.
MLA Zhu, N,et al."Preparation of poly (styrene-co-4-vinyl pyridine) /silica nanoscale hybrids supported cyclopentadienyltitanium trichloride (CpTiCl3) catalyst and styrene polymerization".CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE 22.12(2001):2117-2119.
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