ICCAS OpenIR
Cosolvent effect on the tautomerism of ethyl acetoacetate in supercritical CO2
Li, HP; Zhang, HF; Liu, J; Han, BX
2001-04-01
Source PublicationCHINESE CHEMICAL LETTERS
ISSN1001-8417
Volume12Issue:4Pages:351-352
AbstractThe effect of cosolvent cyclohexane, chloroform, and acetonitrile on the keto-enol tautomeric equilibrium of ethyl acetoacetate in supercritical CO2 was studied by UV-Vis spectroscopy over the pressure range from 76 to 110 bar at 308.15 K. It was found that the equilibrium constant decreases with increasing polarity of the cosolvents.
KeywordSupercritical Co2 Cosolvent Effect Ethyl Acetoacetate Tautomerism
Indexed BySCI
Language英语
WOS IDWOS:000168213100023
PublisherCHINESE CHEMICAL SOCIETY
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Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/77180
Collection中国科学院化学研究所
AffiliationChinese Acad Sci, Inst Chem, Ctr Mol Sci, Beijing 100080, Peoples R China
Recommended Citation
GB/T 7714
Li, HP,Zhang, HF,Liu, J,et al. Cosolvent effect on the tautomerism of ethyl acetoacetate in supercritical CO2[J]. CHINESE CHEMICAL LETTERS,2001,12(4):351-352.
APA Li, HP,Zhang, HF,Liu, J,&Han, BX.(2001).Cosolvent effect on the tautomerism of ethyl acetoacetate in supercritical CO2.CHINESE CHEMICAL LETTERS,12(4),351-352.
MLA Li, HP,et al."Cosolvent effect on the tautomerism of ethyl acetoacetate in supercritical CO2".CHINESE CHEMICAL LETTERS 12.4(2001):351-352.
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