Crystallization behavior of PCL in hybrid confined environment
Jiang, SC; Ji, XL; An, LJ; Jiang, BZ
Source PublicationPOLYMER
AbstractPoly(epsilon -caprolactone) (PCL) and silica (SiO2) organic-inorganic hybrid materials have been synthesized by the sol-gel method. The crystallization behavior of PCL in silica networks has been investigated using differential scanning calorimetry (DSC) and scanning electron microscopy (SEM). The degree of PCL crystallinity in PCL/SiO2 hybrid networks reduces with increase of SiO2. PCL is in an amorphous state when the concentration of PCL is lower than 40wt% in the hybrid system. The melting point of PCL in the networks is lower than, but close to that of pure PCL. WAXD and SEM results show that the crystalline behavior of PCL in PCL/SiO2 hybrid system is strictly confined. (C) 2001 Elsevier Science Ltd. All rights reserved.
KeywordPcl Crystallization Behavior Pcl/sio2 Hybrid
Indexed BySCI
WOS IDWOS:000166619700064
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Cited Times:102[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Corresponding AuthorJiang, SC
AffiliationChinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China
Recommended Citation
GB/T 7714
Jiang, SC,Ji, XL,An, LJ,et al. Crystallization behavior of PCL in hybrid confined environment[J]. POLYMER,2001,42(8):3901-3907.
APA Jiang, SC,Ji, XL,An, LJ,&Jiang, BZ.(2001).Crystallization behavior of PCL in hybrid confined environment.POLYMER,42(8),3901-3907.
MLA Jiang, SC,et al."Crystallization behavior of PCL in hybrid confined environment".POLYMER 42.8(2001):3901-3907.
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