ICCAS OpenIR
Enantiomeric recognition of chiral 3,3-bridged-1,1 '-binaphthol dimer toward alpha-phenylethylamine and alpha-amino acid ester
Liu, TJ; Chen, YJ; Zhang, KS; Wang, D; Guo, DW; Yang, XZ
2001-10-01
Source PublicationCHIRALITY
ISSN0899-0042
Volume13Issue:9Pages:595-600
AbstractThe 1,1'-binaphthol-based dimers with p-phenylenebis(2-ethynyl) spacer, (+)-6 and (+)-2, were synthesized as chiral host compounds. H-1 NMR, UV-vis, and fluorescent titration were used to evaluate the enantiomeric recognition abilities of the chiral host dimers toward the guest amine 7 and alpha -amino acid ester 8. The chiral BINOL-based dimers were found to have good enantiomeric recognition ability. The computer simulation of the host-guest complex molecules was carried out to describe the conformational changes of both naphthyl ring in the molecule of chiral host dimer after complexation with the guest molecule. Chirality 13:595-600, 2001. (C) 2001 Wiley-Liss, Inc.
KeywordEnantiomeric Recognition Alpha-phenylethyl Amine Alpha-amino Acid Ester Chiral 1 1 '-binaphthol-based Dimer
Indexed BySCI
Language英语
WOS IDWOS:000171403500013
PublisherWILEY-LISS
Citation statistics
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/77166
Collection中国科学院化学研究所
Corresponding AuthorWang, D
AffiliationChinese Acad Sci, Inst Chem, Ctr Mol Sci, Polymer Phys Lab, Beijing 100080, Peoples R China
Recommended Citation
GB/T 7714
Liu, TJ,Chen, YJ,Zhang, KS,et al. Enantiomeric recognition of chiral 3,3-bridged-1,1 '-binaphthol dimer toward alpha-phenylethylamine and alpha-amino acid ester[J]. CHIRALITY,2001,13(9):595-600.
APA Liu, TJ,Chen, YJ,Zhang, KS,Wang, D,Guo, DW,&Yang, XZ.(2001).Enantiomeric recognition of chiral 3,3-bridged-1,1 '-binaphthol dimer toward alpha-phenylethylamine and alpha-amino acid ester.CHIRALITY,13(9),595-600.
MLA Liu, TJ,et al."Enantiomeric recognition of chiral 3,3-bridged-1,1 '-binaphthol dimer toward alpha-phenylethylamine and alpha-amino acid ester".CHIRALITY 13.9(2001):595-600.
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