ICCAS OpenIR
Preparation of a new ladderlike oligosilsesquioxane with lateral aryl ester group
Ji, SX; Xu, H; Zhou, XS; Dai, DR; Zhang, RB
2001
Source PublicationREACTIVE & FUNCTIONAL POLYMERS
ISSN1381-5148
Volume50Issue:1Pages:23-31
AbstractA new soluble ladder-like polysilsesquioxane with polar lateral aryl ester group, which has good adhesion properties and could be potential precursors of advanced functional materials such as catalyst carriers, polymeric solid electrolytes and microelectronic packaging materials etc., was successfully synthesized by stepwise coupling polymerization (SCP) method. The monomer used, methyl 4-trichlorosilylpropoxybenzoate, was synthesized by hydrosilylation reaction catalyzed by dicyclopentadienylplatinum(II) dichloride (Cp2PtCl2). The titled polymer was characterized by H-1 NMR, Si-29 NMR, FTIR, X-ray diffraction (XRD) and gel permeation chromatography (GPC). The characterization data demonstrate that the polymer possesses a typical ladder-like structure. (C) 2001 Published by Elsevier Science B.V.
KeywordOligosilsesquioxane Stepwise Coupling Polymerization Hydrosilylation Ladderlike Lateral
Indexed BySCI
Language英语
WOS IDWOS:000172226500003
PublisherELSEVIER SCIENCE BV
Citation statistics
Cited Times:4[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/77132
Collection中国科学院化学研究所
Corresponding AuthorDai, DR
AffiliationChinese Acad Sci, Inst Chem, Ctr Mol Sci, Beijing 100080, Peoples R China
Recommended Citation
GB/T 7714
Ji, SX,Xu, H,Zhou, XS,et al. Preparation of a new ladderlike oligosilsesquioxane with lateral aryl ester group[J]. REACTIVE & FUNCTIONAL POLYMERS,2001,50(1):23-31.
APA Ji, SX,Xu, H,Zhou, XS,Dai, DR,&Zhang, RB.(2001).Preparation of a new ladderlike oligosilsesquioxane with lateral aryl ester group.REACTIVE & FUNCTIONAL POLYMERS,50(1),23-31.
MLA Ji, SX,et al."Preparation of a new ladderlike oligosilsesquioxane with lateral aryl ester group".REACTIVE & FUNCTIONAL POLYMERS 50.1(2001):23-31.
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