ICCAS OpenIR
Mechanism of electroreduction of allyl alcohol at platinized platinum electrode in acidic aqueous solution
Huang, SK; Song, YQ; Zhang, JD; Sun, J
2001-06-29
Source PublicationJOURNAL OF ORGANIC CHEMISTRY
ISSN0022-3263
Volume66Issue:13Pages:4487-4493
AbstractThe electroreduction of allyl alcohol to form propene at the platinized platinum electrode in acidic aqueous solution has been studied using CV plots, IR, ESR, and MS spectra, and a semiempricial MO method (MOPAC7/AM1, PM3). From the determinations of charge-transfer coefficients, reaction orders and apparent activation energy for the given reaction, the detection of the intermediates such as C3H5+, C3H5., and C3H5- species, and PM3 calculations of charge distribution and frontier orbital energies of the reaction species C3H5OH and C3H5+, the authors suggest that in acidic aqueous solution the production of propene via reductive splitting of the C-OH bond situated in the allyl position of allyl alcohol obeys a carbonium ion-carbanion mechanism.
DOI10.1021/jo0012288
Indexed BySCI
Language英语
WOS IDWOS:000169536700004
PublisherAMER CHEMICAL SOC
Citation statistics
Cited Times:3[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/77114
Collection中国科学院化学研究所
Corresponding AuthorHuang, SK
Affiliation1.Hunan Univ, Coll Chem & Chem Engn, Changsha 410082, Peoples R China
2.Changsha Elect Power Inst, Dept Chem, Changsha 410077, Peoples R China
3.Acad Sinica, Inst Chem, Beijing 100080, Peoples R China
Recommended Citation
GB/T 7714
Huang, SK,Song, YQ,Zhang, JD,et al. Mechanism of electroreduction of allyl alcohol at platinized platinum electrode in acidic aqueous solution[J]. JOURNAL OF ORGANIC CHEMISTRY,2001,66(13):4487-4493.
APA Huang, SK,Song, YQ,Zhang, JD,&Sun, J.(2001).Mechanism of electroreduction of allyl alcohol at platinized platinum electrode in acidic aqueous solution.JOURNAL OF ORGANIC CHEMISTRY,66(13),4487-4493.
MLA Huang, SK,et al."Mechanism of electroreduction of allyl alcohol at platinized platinum electrode in acidic aqueous solution".JOURNAL OF ORGANIC CHEMISTRY 66.13(2001):4487-4493.
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