ICCAS OpenIR
Third-order nonlinear optical properties of new square planar complexes with donor-metal-acceptor structure
Yang, CL; Qin, JG; Yang, QG; Si, JH; Wang, SB; Wang, YG; Ye, PX; Ye, C
2001-03-15
Source PublicationSYNTHETIC METALS
ISSN0379-6779
Volume121Issue:1-3Pages:1491-1492
AbstractA new series of mixed-ligand square planar complexes with donor-metal-acceptor (D-M-A) structure (D = pyridine, gamma -methylpyridine, 2,2 ' -bipyridine (bpy) or 1,10-phenanthroline (phen); M = Ni, Pd or Pt; A = maleonitriledithiolate or 4,5-dimercapto-1,3-dithiole-2-thionate) were designed and synthesized for the study of third order nonlinear optical property. The results indicate that complexes containing dmit (dmit = 4,5-dimercapto-1,3-dithiole-2-thionate) exhibit larger third-order optical nonlinearity (gamma (1111) in the order of 10(-31) esu) at 1064 nm than the other complexes. The excited-state enhancement of the third-order nonlinear optical susceptibility of the complex (Py)(2)Pt(mnt) (Py = pyridine, mnt = maleonitriledithiolate) was observed when the sample was optically pumped by either a picosecond or a nanosecond pump beam of wavelength of 355 nm.
KeywordSynthesis Nonlinear Optical Methods
Indexed ByISTP ; SCI
Language英语
WOS IDWOS:000168831200188
PublisherELSEVIER SCIENCE SA
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Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/76876
Collection中国科学院化学研究所
Corresponding AuthorQin, JG
Affiliation1.Wuhan Univ, Dept Chem, Wuhan 430072, Peoples R China
2.Chinese Acad Sci, Inst Phys, Beijing 100080, Peoples R China
3.Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China
Recommended Citation
GB/T 7714
Yang, CL,Qin, JG,Yang, QG,et al. Third-order nonlinear optical properties of new square planar complexes with donor-metal-acceptor structure[J]. SYNTHETIC METALS,2001,121(1-3):1491-1492.
APA Yang, CL.,Qin, JG.,Yang, QG.,Si, JH.,Wang, SB.,...&Ye, C.(2001).Third-order nonlinear optical properties of new square planar complexes with donor-metal-acceptor structure.SYNTHETIC METALS,121(1-3),1491-1492.
MLA Yang, CL,et al."Third-order nonlinear optical properties of new square planar complexes with donor-metal-acceptor structure".SYNTHETIC METALS 121.1-3(2001):1491-1492.
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