ICCAS OpenIR
Synthesis and photochromic property of ethylenediammonium polymolybdate NH3CH2CH2NH3Mo3O10 center dot 4.4H(2)O
Shao, K; Ma, Y; Chen, ZH; Zhang, XT; He, T; Yao, JN; Liu, T; Zhang, J; Hu, TD
2001
Source PublicationACTA CHIMICA SINICA
ISSN0567-7351
Volume59Issue:8Pages:1335-1339
AbstractA novel photochromic compound NH3CH2CH2NH3Mo3O10.4.4H(2)O has been synthesized using ethylenediammonium cations as template under mild chemical conditions. Elemental analysis, TGA curve and IR spectra show that its inorganic framework is constructed from infinite chains of (Mo3O10)(infinity)(2-). Ethylenediammonium cations are bounded to the inorganic chain structure through a supramolecular interaction. It is found that this compound has good photochromic property. Differing from vacuum deposited MoO3 film, this compound turns from white to reddish brown after UV irradiation. EXAFS spectra confirm proton transfer from ethylenediammonium cations to Mo-O- after UV irradiation.
KeywordEthylenediammonium Molybdate Synthesis Photochromic Property
Indexed BySCI
Language英语
WOS IDWOS:000170513100030
PublisherSCIENCE PRESS
Citation statistics
Cited Times:4[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/76862
Collection中国科学院化学研究所
Corresponding AuthorShao, K
Affiliation1.Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Beijing 100080, Peoples R China
2.Chinese Acad Sci, Inst High Energet Phys, Beijing 100039, Peoples R China
Recommended Citation
GB/T 7714
Shao, K,Ma, Y,Chen, ZH,et al. Synthesis and photochromic property of ethylenediammonium polymolybdate NH3CH2CH2NH3Mo3O10 center dot 4.4H(2)O[J]. ACTA CHIMICA SINICA,2001,59(8):1335-1339.
APA Shao, K.,Ma, Y.,Chen, ZH.,Zhang, XT.,He, T.,...&Hu, TD.(2001).Synthesis and photochromic property of ethylenediammonium polymolybdate NH3CH2CH2NH3Mo3O10 center dot 4.4H(2)O.ACTA CHIMICA SINICA,59(8),1335-1339.
MLA Shao, K,et al."Synthesis and photochromic property of ethylenediammonium polymolybdate NH3CH2CH2NH3Mo3O10 center dot 4.4H(2)O".ACTA CHIMICA SINICA 59.8(2001):1335-1339.
Files in This Item:
There are no files associated with this item.
Related Services
Recommend this item
Bookmark
Usage statistics
Export to Endnote
Google Scholar
Similar articles in Google Scholar
[Shao, K]'s Articles
[Ma, Y]'s Articles
[Chen, ZH]'s Articles
Baidu academic
Similar articles in Baidu academic
[Shao, K]'s Articles
[Ma, Y]'s Articles
[Chen, ZH]'s Articles
Bing Scholar
Similar articles in Bing Scholar
[Shao, K]'s Articles
[Ma, Y]'s Articles
[Chen, ZH]'s Articles
Terms of Use
No data!
Social Bookmark/Share
All comments (0)
No comment.
 

Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.