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Formation and photodissociation of Chromium/Phosphorus binary clusters
Han, CY; Xing, XP; Gao, Z; Zhu, QH
2001-04-01
Source PublicationCHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE
ISSN0251-0790
Volume22Issue:4Pages:622-625
AbstractChromium/Phosphorus binary clusters were produced by direct laser ablation and analyzed by tandem time-of-flight mass spectrometer. The main clusters formed were rich in phosphorus, There is an oscillation in CrPm+ series(the peaks with even m are stronger than those with odd m, especially the peaks of CrP4+ and CrP8+ are the strongest) and this may be ascribed to the specific stability of P-4 structure. There are some strong peaks such as Cr3P8+, Cr4P9+, Cr5P11+, Cr6P12+, Cr8P14+, etc., which don't change with the change of the ratios of Cr to P in the samples, and their stability could be explained with an electron model of valence electrons filling the d orbitals of Cr, The results of photodissociation just accord with the model.
KeywordChromium/phosphorus Clusters Laser Ablation Laser Photodissociation
Indexed BySCI
Language英语
WOS IDWOS:000168362300028
PublisherHIGHER EDUCATION PRESS
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Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/76776
Collection中国科学院化学研究所
Corresponding AuthorGao, Z
AffiliationChinese Acad Sci, Inst Chem, State Key Lab Mol React Dynam, Beijing 100080, Peoples R China
Recommended Citation
GB/T 7714
Han, CY,Xing, XP,Gao, Z,et al. Formation and photodissociation of Chromium/Phosphorus binary clusters[J]. CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,2001,22(4):622-625.
APA Han, CY,Xing, XP,Gao, Z,&Zhu, QH.(2001).Formation and photodissociation of Chromium/Phosphorus binary clusters.CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,22(4),622-625.
MLA Han, CY,et al."Formation and photodissociation of Chromium/Phosphorus binary clusters".CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE 22.4(2001):622-625.
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