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First experimental observation on different ionic states of the CH3CH2O radical: a HeI photoelectron spectrum of the ethoxy CH3CH2O radical
Wang, J; Sun, Z; Zhu, XJ; Ge, MF; Wang, DX
2001-05-25
Source PublicationCHEMICAL PHYSICS LETTERS
ISSN0009-2614
Volume340Issue:1-2Pages:98-102
AbstractA continuous flowing ethoxy CH3CH2O radical beam is produced in situ by pyrolysis of CH3CH2ONO at 223(+/-0.5)degreesC. By combining the HeI photoelectron spectrum with the improved density function theory (DFT) calculation, we have concluded that the CH3CH2O radical has C, symmetry and the ground state of the CH3CH2O+ cation is the (3)A " State which comes from removal of an electron of the SHOMO 10a ' orbital for the CH3CH2O radical. Both the photoelectron spectroscopy (PES) experiment and the DFT calculations not only provide another example of exchanging order of the ionic states for the species studied, but also the first example in which there has been almost the same vibrational structure on different ionic states caused by electron ionization on an orbital. (C) 2001 Elsevier Science B.V. All rights reserved.
Indexed BySCI
Language英语
WOS IDWOS:000169051900015
PublisherELSEVIER SCIENCE BV
Citation statistics
Cited Times:12[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/76706
Collection中国科学院化学研究所
Corresponding AuthorWang, DX
AffiliationChinese Acad Sci, Inst Chem, Ctr Mol Sci, Beijing 100080, Peoples R China
Recommended Citation
GB/T 7714
Wang, J,Sun, Z,Zhu, XJ,et al. First experimental observation on different ionic states of the CH3CH2O radical: a HeI photoelectron spectrum of the ethoxy CH3CH2O radical[J]. CHEMICAL PHYSICS LETTERS,2001,340(1-2):98-102.
APA Wang, J,Sun, Z,Zhu, XJ,Ge, MF,&Wang, DX.(2001).First experimental observation on different ionic states of the CH3CH2O radical: a HeI photoelectron spectrum of the ethoxy CH3CH2O radical.CHEMICAL PHYSICS LETTERS,340(1-2),98-102.
MLA Wang, J,et al."First experimental observation on different ionic states of the CH3CH2O radical: a HeI photoelectron spectrum of the ethoxy CH3CH2O radical".CHEMICAL PHYSICS LETTERS 340.1-2(2001):98-102.
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