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Synthesis and crystal structure of 13-phenyl-1,10-dithia-4,7-dioxa-13-aza-15-Crown-5
Jiang, H; Chen, LR; Niu, CR
2001
Source PublicationCHINESE JOURNAL OF STRUCTURAL CHEMISTRY
ISSN0254-5861
Volume20Issue:2Pages:83-87
AbstractCrystal structure of the title Compound C-16 H-25 O-2 NS2 has been determined by Xray diffraction method. Its crystallographic data were as follows: M-r = 327.51, triclinic, space group P1, a = 8.864(3), b = 10.127(4), c = 10.390(3) Angstrom, alpha = 105.94(3), beta = 103.10(2), gamma = 90.96(3)degrees, V = 870.3(7) Angstrom (3), Z = 2, D-c = 1.250g.cm(-3), mu (MoK alpha) = 2.966cm(-1), F(000) = 176, a total of 3275 reflections measured (2 theta (max) = 50 degrees), 2246 [I greater than or equal to 5 sigma (I)] used in the refinement, R = 0.067, R-w = 0.082. The result shows that the distances of N(1) - C(2) and N(1) - C(3) are longer than that of N(1) - C(11), which indicates that the interaction of C-Lambdar - N-sp(2) is stronger than that of C-sp(3) - N-sp(2). Oxygen, nitrogen and sulfur atoms of the ring in the same plane was deduced from the least-squares planes and the dihedral angles.
KeywordCrystal Structure Mixed-donor Crown Ether Synthesis
Indexed BySCI
Language英语
WOS IDWOS:000167883800001
PublisherCHINESE JOURNAL STRUCTURAL CHEMISTRY
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Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/76630
Collection中国科学院化学研究所
Corresponding AuthorJiang, H
Affiliation1.Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Lab Photochem, Beijing 100080, Peoples R China
2.Wuhan Univ, Ctr Anal & Testing, Wuhan 430072, Peoples R China
3.Wuhan Univ, Coll Chem & Environm Sci, Wuhan 430072, Peoples R China
Recommended Citation
GB/T 7714
Jiang, H,Chen, LR,Niu, CR. Synthesis and crystal structure of 13-phenyl-1,10-dithia-4,7-dioxa-13-aza-15-Crown-5[J]. CHINESE JOURNAL OF STRUCTURAL CHEMISTRY,2001,20(2):83-87.
APA Jiang, H,Chen, LR,&Niu, CR.(2001).Synthesis and crystal structure of 13-phenyl-1,10-dithia-4,7-dioxa-13-aza-15-Crown-5.CHINESE JOURNAL OF STRUCTURAL CHEMISTRY,20(2),83-87.
MLA Jiang, H,et al."Synthesis and crystal structure of 13-phenyl-1,10-dithia-4,7-dioxa-13-aza-15-Crown-5".CHINESE JOURNAL OF STRUCTURAL CHEMISTRY 20.2(2001):83-87.
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