Novel network polymer electrolytes based on polysiloxane with internal plasticizer
Zhang, ZC; Fang, SB
AbstractA novel network polymer electrolyte based on the polymethylsiloxane system has been designed and synthesized. In the network polymers, different numbers of PEG chains with various molecular weights were introduced onto the networks as immobile internal plasticizer through a hydrosilylation reaction. The presence of internal plasticizers pendant on the network backbones can lower the glass transition temperatures (T-g) of the electrolytes, make the lithium salt easily dissolved and accelerate the migration of free lithium ions migration. The ambient ionic conductivity (sigma(RT)) was significantly enhanced compared with that of network polymer electrolytes without internal plasticizers. The optimum ionic conductivity was 10(-4.1) S cm(-1) at room temperature and 10(-3.0) S cm(-1) at 80 degrees C. (C) 2000 Elsevier Science Ltd. All rights reserved.
KeywordNetwork Polymer Electrolytes Internal Plasticizing Chains Hydrosilylation Reaction Ionic Conductivity Vtf Equation
Indexed BySCI
WOS IDWOS:000086007100011
Citation statistics
Document Type期刊论文
Corresponding AuthorFang, SB
AffiliationChinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China
Recommended Citation
GB/T 7714
Zhang, ZC,Fang, SB. Novel network polymer electrolytes based on polysiloxane with internal plasticizer[J]. ELECTROCHIMICA ACTA,2000,45(13):2131-2138.
APA Zhang, ZC,&Fang, SB.(2000).Novel network polymer electrolytes based on polysiloxane with internal plasticizer.ELECTROCHIMICA ACTA,45(13),2131-2138.
MLA Zhang, ZC,et al."Novel network polymer electrolytes based on polysiloxane with internal plasticizer".ELECTROCHIMICA ACTA 45.13(2000):2131-2138.
Files in This Item:
There are no files associated with this item.
Related Services
Recommend this item
Usage statistics
Export to Endnote
Google Scholar
Similar articles in Google Scholar
[Zhang, ZC]'s Articles
[Fang, SB]'s Articles
Baidu academic
Similar articles in Baidu academic
[Zhang, ZC]'s Articles
[Fang, SB]'s Articles
Bing Scholar
Similar articles in Bing Scholar
[Zhang, ZC]'s Articles
[Fang, SB]'s Articles
Terms of Use
No data!
Social Bookmark/Share
All comments (0)
No comment.

Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.