ICCAS OpenIR
Transition metal acetylide catalysts for polymerization of polar alkynes
Zhan, XW; Yang, MJ; Sun, HM
2000
Source PublicationCATALYSIS LETTERS
ISSN1011-372X
Volume70Issue:1-2Pages:79-82
AbstractA new series of single-component air-stable transition metal acetylide catalysts with the structures ML2(C=CR)(2) (M=Ni and Pd, L=PPh3 and PBu3, R=p-C6H4C=CH, C6H5, H, CH2OH, CH2OCOCH3, CH2OCOC6H5 and CH2OCOC6H4OH-o) for polymerization of polar alkynes were developed. Transition metals, phosphine and alkynyl ligands and solvents exhibited significant influence on the polymerization. Propargyl alcohol could be polymerized with these catalysts under mild conditions to give soluble rich-trans polymers with weight average molecular weights as high as 5.7x10(4) in yields as high as 79%.
KeywordPolymerization Propargyl Alcohol Poly(Propargyl Alcohol) Transition Metal Acetylide Catalyst
Indexed BySCI
Language英语
WOS IDWOS:000165179200013
PublisherSPRINGER
Citation statistics
Cited Times:18[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/76446
Collection中国科学院化学研究所
Corresponding AuthorYang, MJ
Affiliation1.Zhejiang Univ, Dept Polymer Sci & Engn, Hangzhou 310027, Peoples R China
2.Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China
3.Suzhou Univ, Sch Chem & Chem Engn, Suzhou 215006, Peoples R China
Recommended Citation
GB/T 7714
Zhan, XW,Yang, MJ,Sun, HM. Transition metal acetylide catalysts for polymerization of polar alkynes[J]. CATALYSIS LETTERS,2000,70(1-2):79-82.
APA Zhan, XW,Yang, MJ,&Sun, HM.(2000).Transition metal acetylide catalysts for polymerization of polar alkynes.CATALYSIS LETTERS,70(1-2),79-82.
MLA Zhan, XW,et al."Transition metal acetylide catalysts for polymerization of polar alkynes".CATALYSIS LETTERS 70.1-2(2000):79-82.
Files in This Item:
There are no files associated with this item.
Related Services
Recommend this item
Bookmark
Usage statistics
Export to Endnote
Google Scholar
Similar articles in Google Scholar
[Zhan, XW]'s Articles
[Yang, MJ]'s Articles
[Sun, HM]'s Articles
Baidu academic
Similar articles in Baidu academic
[Zhan, XW]'s Articles
[Yang, MJ]'s Articles
[Sun, HM]'s Articles
Bing Scholar
Similar articles in Bing Scholar
[Zhan, XW]'s Articles
[Yang, MJ]'s Articles
[Sun, HM]'s Articles
Terms of Use
No data!
Social Bookmark/Share
All comments (0)
No comment.
 

Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.