ICCAS OpenIR
Two-phase hydroformylation reaction catalysed by rhodium-complexed water-soluble dendrimers
Gong, AJ; Fan, QH; Chen, YM; Liu, HW; Chen, CF; Xi, F
2000-10-02
Source PublicationJOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL
ISSN1381-1169
Volume159Issue:2Pages:225-232
AbstractFour water-soluble dendritic phosphonated Ligands were first synthesized based on poly(amidoamine) (PAMAM) (generation 3 with 32 cascade end groups), with the hydrophilic amine or sulfonic acid groups on the surface of the dendrimer. Their Rh(I) complexes were used as the catalysts in the two-phase hydroformylation of styrene and 1-octene at mild reaction conditions. The results showed that these new water-soluble dendritic catalysts exhibited high catalytic activity both for 1-octene and styrene. These new catalysts also exhibited high selectivity for the iso-aromatic aldehyde, while in the long chain olefin case the selectivity was benefited for normal aldehyde. (C) 2000 Elsevier Science B.V. All rights reserved.
KeywordDendrimer Water-soluble Ligand Two-phase Hydroformylation
Indexed BySCI
Language英语
WOS IDWOS:000089431200008
PublisherELSEVIER SCIENCE BV
Citation statistics
Cited Times:35[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/76430
Collection中国科学院化学研究所
Corresponding AuthorXi, F
AffiliationChinese Acad Sci, Inst Chem, Ctr Mol Sci, PCLCC, Beijing 100080, Peoples R China
Recommended Citation
GB/T 7714
Gong, AJ,Fan, QH,Chen, YM,et al. Two-phase hydroformylation reaction catalysed by rhodium-complexed water-soluble dendrimers[J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL,2000,159(2):225-232.
APA Gong, AJ,Fan, QH,Chen, YM,Liu, HW,Chen, CF,&Xi, F.(2000).Two-phase hydroformylation reaction catalysed by rhodium-complexed water-soluble dendrimers.JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL,159(2),225-232.
MLA Gong, AJ,et al."Two-phase hydroformylation reaction catalysed by rhodium-complexed water-soluble dendrimers".JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL 159.2(2000):225-232.
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