ICCAS OpenIR
Synthesis and cation-mediated electron transfer in intramolecular fluorescence quenching of donor-acceptor podands: observation of Marcus inverted region in forward electron transfer reactions
Jiang, H; Xu, HJ; Ye, JP
2000-05-01
Source PublicationJOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2
ISSN1472-779X
Volume5Pages:925-930
AbstractThe synthesis of a series of donor-acceptor podands is described. The dependence of the rate constants of intramolecular photoinduced electron transfer on the exothermicity of the reaction was studied by stationary and time-resolved fluorescence spectroscopy. H-1 NMR and computational studies suggest that the conformational change of the podands is restricted by K+ binding. As a result, the occurrence of highly exothermic photoinduced electron transfer reaction within the Marcus inverted region was observed.
Indexed BySCI ; IC
Language英语
WOS IDWOS:000087106300005
PublisherROYAL SOC CHEMISTRY
Citation statistics
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/76416
Collection中国科学院化学研究所
Corresponding AuthorXu, HJ
AffiliationChinese Acad Sci, Inst Chem, Ctr Mol Sci, Lab Photochem, Beijing 100080, Peoples R China
Recommended Citation
GB/T 7714
Jiang, H,Xu, HJ,Ye, JP. Synthesis and cation-mediated electron transfer in intramolecular fluorescence quenching of donor-acceptor podands: observation of Marcus inverted region in forward electron transfer reactions[J]. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2,2000,5:925-930.
APA Jiang, H,Xu, HJ,&Ye, JP.(2000).Synthesis and cation-mediated electron transfer in intramolecular fluorescence quenching of donor-acceptor podands: observation of Marcus inverted region in forward electron transfer reactions.JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2,5,925-930.
MLA Jiang, H,et al."Synthesis and cation-mediated electron transfer in intramolecular fluorescence quenching of donor-acceptor podands: observation of Marcus inverted region in forward electron transfer reactions".JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2 5(2000):925-930.
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