ICCAS OpenIR
Preparation of a methylsulfo-methylcellulose-Pd complex and its catalytic behaviors in asymmetric hydrogenation of o-cresol
Mao, BW; Zhao, AG; Huang, MY; Jiang, YY
2000-05-01
Source PublicationPOLYMERS FOR ADVANCED TECHNOLOGIES
ISSN1042-7147
Volume11Issue:5Pages:254-257
AbstractA new chiral polymer-metal complex, methylsulfomethyl-cellulose-Pd complex (MS-MC-Pd) was prepared by the reaction of methylcellulose with methylsulfonyl chloride, followed by reaction with palladium chloride. The complex obtained was found to catalyze the asymmetric hydrogenation of o-cresol to give (S)-2-methyl-cyclohexanone in more than 90% product and optical yields at 25 degrees C and under 1 atm H-2. The product and optical yields were greatly affected by Pd lending in the complex, solvent quality and reaction temperature. The catalyst could be reused several times without any remarkable loss in optical catalytic activity. Copyright (C) 2000 John Wiley & Sons, Ltd.
KeywordMethylsulfo-methylcellulose Pd Complex Chiral Catalyst Asymmetric Hydrogenation O-cresol
Indexed ByISTP ; SCI
Language英语
WOS IDWOS:000087653200008
PublisherJOHN WILEY & SONS LTD
Citation statistics
Cited Times:1[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/76402
Collection中国科学院化学研究所
Corresponding AuthorMao, BW
AffiliationChinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China
Recommended Citation
GB/T 7714
Mao, BW,Zhao, AG,Huang, MY,et al. Preparation of a methylsulfo-methylcellulose-Pd complex and its catalytic behaviors in asymmetric hydrogenation of o-cresol[J]. POLYMERS FOR ADVANCED TECHNOLOGIES,2000,11(5):254-257.
APA Mao, BW,Zhao, AG,Huang, MY,&Jiang, YY.(2000).Preparation of a methylsulfo-methylcellulose-Pd complex and its catalytic behaviors in asymmetric hydrogenation of o-cresol.POLYMERS FOR ADVANCED TECHNOLOGIES,11(5),254-257.
MLA Mao, BW,et al."Preparation of a methylsulfo-methylcellulose-Pd complex and its catalytic behaviors in asymmetric hydrogenation of o-cresol".POLYMERS FOR ADVANCED TECHNOLOGIES 11.5(2000):254-257.
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