ICCAS OpenIR
Asymmetric hydrogenation of salicyl alcohol catalyzed by methylsulfo-sodium carboxymethylcellulose-Pt complex
Mao, BW; Zhao, AG; Huang, MY; Jiang, YY
2000-05-01
Source PublicationPOLYMERS FOR ADVANCED TECHNOLOGIES
ISSN1042-7147
Volume11Issue:5Pages:250-253
AbstractA new chiral polymer-metal complex, methylsulfosodium carboxymethyl-cellulose-Pt complex (MS-NaCMC-Pt), has been prepared by the reaction of sodium carboxymethylcellulose with methylsulfonyl chloride and H2PtCl6. 6H(2), which was found to he able to catalyze the asymmetric hydrogenation of salicyl alcohol to give (1S,2S)-2-(hydroxymethyl)-cyclohexanol at 28 degrees C and under 1 atm H-2, in > 90% product and optical yields, respectively. The catalyst could be reused many times without any remarkable changes in optical catalytic activity. Copyright (C) 2000 John Wiley & Sons, Ltd.
KeywordMethylsulfo-sodium Carboxymethylcellulose Pt Complex Chiral Catalyst Asymmetric Hydrogenation Salicyl Alcohol
Indexed ByISTP ; SCI
Language英语
WOS IDWOS:000087653200007
PublisherJOHN WILEY & SONS LTD
Citation statistics
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/76098
Collection中国科学院化学研究所
Corresponding AuthorMao, BW
AffiliationChinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China
Recommended Citation
GB/T 7714
Mao, BW,Zhao, AG,Huang, MY,et al. Asymmetric hydrogenation of salicyl alcohol catalyzed by methylsulfo-sodium carboxymethylcellulose-Pt complex[J]. POLYMERS FOR ADVANCED TECHNOLOGIES,2000,11(5):250-253.
APA Mao, BW,Zhao, AG,Huang, MY,&Jiang, YY.(2000).Asymmetric hydrogenation of salicyl alcohol catalyzed by methylsulfo-sodium carboxymethylcellulose-Pt complex.POLYMERS FOR ADVANCED TECHNOLOGIES,11(5),250-253.
MLA Mao, BW,et al."Asymmetric hydrogenation of salicyl alcohol catalyzed by methylsulfo-sodium carboxymethylcellulose-Pt complex".POLYMERS FOR ADVANCED TECHNOLOGIES 11.5(2000):250-253.
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