ICCAS OpenIR
Synthesis of phenylacetic acid by carbonylation
Duan, JR; Jiang, J; Gong, JF; Fan, QH; Jiang, DZ
2000-09-22
Source PublicationJOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL
ISSN1381-1169
Volume159Issue:1Pages:89-96
AbstractThe carbonylation of benzyl alcohol to phenylacetic acid and its derivatives in the presence of rhodium catalysts is reported in this work. The influence of different reaction conditions, such as total reaction pressure, hydrogen partial pressure, catalyst, promoter and reactant concentrations, as well as reaction temperature on the catalytic activity and selectivity has been investigated. The activation parameters of the carbonylation have been measured and a possible mechanism of the reaction has been proposed. (C) 2000 Elsevier Science B.V. All rights reserved.
KeywordBenzyl Alcohol Phenylacetic Acid Carbonylation Rhodium Catalyst
Indexed ByISTP ; SCI
Language英语
WOS IDWOS:000089387500014
PublisherELSEVIER SCIENCE BV
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Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/76072
Collection中国科学院化学研究所
Corresponding AuthorJiang, DZ
AffiliationChinese Acad Sci, Inst Chem, Ctr Mol Sci, Beijing 100080, Peoples R China
Recommended Citation
GB/T 7714
Duan, JR,Jiang, J,Gong, JF,et al. Synthesis of phenylacetic acid by carbonylation[J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL,2000,159(1):89-96.
APA Duan, JR,Jiang, J,Gong, JF,Fan, QH,&Jiang, DZ.(2000).Synthesis of phenylacetic acid by carbonylation.JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL,159(1),89-96.
MLA Duan, JR,et al."Synthesis of phenylacetic acid by carbonylation".JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL 159.1(2000):89-96.
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