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Study on transition metal-4,5-dimercapto-1,3-dithiole-2-one complexes and related compounds: toward structure-property correlation
Liu, SG; Liu, YQ; Li, YF; Zhu, DB
2000-08-01
Source PublicationSYNTHETIC METALS
ISSN0379-6779
Volume114Issue:2Pages:139-146
AbstractElectrical and electrochemical properties of a series of metal bisdithiolene ion-pair charge transfer complexes of 1,3-dithiole-2-one-4,5-dithiolate, 1,3-dithiole-2-thione-4,5 -dithiolate, 1,3-dithiole-2-selone-4,5-dithiolate, and 5,6-dihydro-1,4-dithiin-2,3-dithiolate ligands with general formula [C](x)[ML2] (C = counter cation, such as tetrabutylammonium, tetraethylammonium, and tetramethylammonium; M = Ni, Cu, Zn, Pd, or Pt; x = 1, 2 or non-integer; L = ligand) have been studied and compared to each other. The effects of the central chelating metal ion, counter cation, stoichiometry, and the ligand on the electrical and electrochemical behaviour are discussed. A crystal structure of bis(tetrabutylammonium) bis(1,3-dithione-2-one-4,5-dithiolato)zincate is determined and compared with its analog compounds. Structure-property relationships are discussed. (C) 2000 Elsevier Science S.A. All rights reserved.
KeywordElectrical And Chemical Properties Structure-property Relationships Transition Metal-4 5-dimercapto-1 3-dithiole-2-one Complexes
Indexed BySCI
Language英语
WOS IDWOS:000088192900008
PublisherELSEVIER SCIENCE SA
Citation statistics
Cited Times:4[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/75952
Collection中国科学院化学研究所
Corresponding AuthorLiu, SG
AffiliationChinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China
Recommended Citation
GB/T 7714
Liu, SG,Liu, YQ,Li, YF,et al. Study on transition metal-4,5-dimercapto-1,3-dithiole-2-one complexes and related compounds: toward structure-property correlation[J]. SYNTHETIC METALS,2000,114(2):139-146.
APA Liu, SG,Liu, YQ,Li, YF,&Zhu, DB.(2000).Study on transition metal-4,5-dimercapto-1,3-dithiole-2-one complexes and related compounds: toward structure-property correlation.SYNTHETIC METALS,114(2),139-146.
MLA Liu, SG,et al."Study on transition metal-4,5-dimercapto-1,3-dithiole-2-one complexes and related compounds: toward structure-property correlation".SYNTHETIC METALS 114.2(2000):139-146.
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