ICCAS OpenIR
Synthesis and characterization of fully soluble polyphenylenevinylene
Pan, JQ; Chen, ZK; Xiao, Y; Huang, W
2000-11-01
Source PublicationCHINESE JOURNAL OF POLYMER SCIENCE
ISSN0256-7679
Volume18Issue:6Pages:541-549
AbstractFully soluble poly[2-methoxy-5-(2'-ethylhexyl)-oxy)-p-phenylenevinylene] (MEH-PPV) was synthesized by the addition of molecular weight modifiers (chain stopper, Free radical scavengers) to a polymerization system containing monomer, catalyst and a solvent. These PPV products synthesized in this work were characterized by IR, NMR, UV-visible spectroscopy and GPC. Results show that the M-w of polyphenylvinylene (PPV) can be controlled by the addition of chain stopper (benzyl bromide) and radical inhibitor (2,6-di-tert-butyl-4-methyl phenol). The polymerization mechanism in the presence of these additives was also discussed. A dual mechanism involving carbene for PPV polymerization was proposed.
KeywordPolyphenylenevinylene Light Emitting Polymer Conjugation Polymer Conducting Polymer Polymerization Of Ppv
Indexed BySCI
Language英语
WOS IDWOS:000165081000009
PublisherSPRINGER-VERLAG BERLIN
Citation statistics
Cited Times:6[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/75742
Collection中国科学院化学研究所
Corresponding AuthorPan, JQ
Affiliation1.Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China
2.Natl Univ Singapore, Inst Mat Res & Engn, Singapore 119260, Singapore
Recommended Citation
GB/T 7714
Pan, JQ,Chen, ZK,Xiao, Y,et al. Synthesis and characterization of fully soluble polyphenylenevinylene[J]. CHINESE JOURNAL OF POLYMER SCIENCE,2000,18(6):541-549.
APA Pan, JQ,Chen, ZK,Xiao, Y,&Huang, W.(2000).Synthesis and characterization of fully soluble polyphenylenevinylene.CHINESE JOURNAL OF POLYMER SCIENCE,18(6),541-549.
MLA Pan, JQ,et al."Synthesis and characterization of fully soluble polyphenylenevinylene".CHINESE JOURNAL OF POLYMER SCIENCE 18.6(2000):541-549.
Files in This Item:
There are no files associated with this item.
Related Services
Recommend this item
Bookmark
Usage statistics
Export to Endnote
Google Scholar
Similar articles in Google Scholar
[Pan, JQ]'s Articles
[Chen, ZK]'s Articles
[Xiao, Y]'s Articles
Baidu academic
Similar articles in Baidu academic
[Pan, JQ]'s Articles
[Chen, ZK]'s Articles
[Xiao, Y]'s Articles
Bing Scholar
Similar articles in Bing Scholar
[Pan, JQ]'s Articles
[Chen, ZK]'s Articles
[Xiao, Y]'s Articles
Terms of Use
No data!
Social Bookmark/Share
All comments (0)
No comment.
 

Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.