ICCAS OpenIR
Atomic force microscopy of oxidative coupling reactions of phenols with FeCl3 in the solid state
Zeng, QD; Wang, C; Bai, CL; Zeng, PJ; Li, Y; Yan, XJ
1999-09-01
Source PublicationJOURNAL OF VACUUM SCIENCE & TECHNOLOGY B
ISSN1071-1023
Volume17Issue:5Pages:1935-1940
AbstractThe solid-solid chemical reactions of phenols or ketones, such as beta-naphthol (1) or anthron (2), with FeCl3. 6H(2)O by ultraviolet irradiation give coupling dimeric products. The mechanisms are studied using atomic force microscopy (AFM) and known crystal packing data. AFM reveals that the crystal face (100) of 2 or (001) of 1 exhibits stumpy protrusions all over the surface from the contact edge of the crystals, respectively, whereas the long side face (010) of 2 gives volcanoes. All of those are guided by the crystal structure. Molecular interpretations of the AFM features are given. (C) 1999 American Vacuum Society. [S0734-211X(99)07705-7].
Indexed BySCI
Language英语
WOS IDWOS:000083129900008
PublisherAMER INST PHYSICS
Citation statistics
Cited Times:2[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/75576
Collection中国科学院化学研究所
Corresponding AuthorZeng, QD
Affiliation1.Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China
2.Chinese Acad Sci, Inst Chem Met, Beijing 100080, Peoples R China
Recommended Citation
GB/T 7714
Zeng, QD,Wang, C,Bai, CL,et al. Atomic force microscopy of oxidative coupling reactions of phenols with FeCl3 in the solid state[J]. JOURNAL OF VACUUM SCIENCE & TECHNOLOGY B,1999,17(5):1935-1940.
APA Zeng, QD,Wang, C,Bai, CL,Zeng, PJ,Li, Y,&Yan, XJ.(1999).Atomic force microscopy of oxidative coupling reactions of phenols with FeCl3 in the solid state.JOURNAL OF VACUUM SCIENCE & TECHNOLOGY B,17(5),1935-1940.
MLA Zeng, QD,et al."Atomic force microscopy of oxidative coupling reactions of phenols with FeCl3 in the solid state".JOURNAL OF VACUUM SCIENCE & TECHNOLOGY B 17.5(1999):1935-1940.
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