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The preparation of zeolite-supported polysiloxane-triphenylphosphine-P complex and its catalytic behavior in hydrogenation
Liu, ZX; Jiang, K; Huang, MY; Jiang, YY
1999
Source PublicationPOLYMERS FOR ADVANCED TECHNOLOGIES
ISSN1042-7147
Volume10Issue:1-2Pages:112-115
AbstractA new phosphine-containing polymer ligand, zeolite-supported polysiloxane-triphenylphosphine (Zeo-SiO-P), has been prepared from zeolite, triphenylphosphine, ethyl orthosilicate and water by a very simple method. A palladium complex of zeolite-supported polysiloxane-triphenylphosphine (Zeo-SiO-P-Pd) has been found to be able to catalyze the hydrogenation of various unsaturated compounds as nitrobenzene and methacrolein to corresponding reduction compounds at 40 degrees C under atmospheric hydrogen pressure in 100% yield. This catalyst is very stable in the hydrogenation anti can be reused several times without appreciable change in catalytic activity. (C) 1999 John Wiley & Sons, Ltd.
KeywordZeolite-supported Complex Catalyst Polysiloxane Phosphine Palladium Hydrogenation
Indexed BySCI
Language英语
WOS IDWOS:000078515800022
PublisherJOHN WILEY & SONS LTD
Citation statistics
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/75514
Collection中国科学院化学研究所
Corresponding AuthorLiu, ZX
AffiliationChinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China
Recommended Citation
GB/T 7714
Liu, ZX,Jiang, K,Huang, MY,et al. The preparation of zeolite-supported polysiloxane-triphenylphosphine-P complex and its catalytic behavior in hydrogenation[J]. POLYMERS FOR ADVANCED TECHNOLOGIES,1999,10(1-2):112-115.
APA Liu, ZX,Jiang, K,Huang, MY,&Jiang, YY.(1999).The preparation of zeolite-supported polysiloxane-triphenylphosphine-P complex and its catalytic behavior in hydrogenation.POLYMERS FOR ADVANCED TECHNOLOGIES,10(1-2),112-115.
MLA Liu, ZX,et al."The preparation of zeolite-supported polysiloxane-triphenylphosphine-P complex and its catalytic behavior in hydrogenation".POLYMERS FOR ADVANCED TECHNOLOGIES 10.1-2(1999):112-115.
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