ICCAS OpenIR
Anodic electrocrystallization of BaKPbO and BaKPbBiO from molten salt
Zhang, L; Zhao, LZ; Zhang, JB; Xu, CY; Liu, SH
1999-11-01
Source PublicationACTA PHYSICO-CHIMICA SINICA
ISSN1000-6818
Volume15Issue:11Pages:1049-1052
AbstractBaKPbO and BaKPbBiO single crystals were electrodeposited on anode by the molten salt electrochemical method using KOH/KNO3 as flux. It is found that the K content decreases when the KNO3 concentration in the flux increases. On the other hand, when the KNO3 concentration in the flux is constant, the K content increases as the Bi content in the BaKPbBiO crystals increases, The magnetic susecptibility measurements show that Ba-K-Pb-Bi-O crystals are super-conducting while BaKPbO crystals are not. XPS analyses reveal that the M(M = Pb, Bi) 6 s - O2p valence band moves toward the Fermi level when the Bi content in BaKPbBiO decreases.
KeywordComplex Oxides Anodic Electrocrystallization Superconductivity Electronic Structure
DOI10.3866/PKU.WHXB19991118
Indexed BySCI
Language英语
WOS IDWOS:000083915100018
PublisherPEKING UNIV PRESS
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Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/75490
Collection中国科学院化学研究所
Corresponding AuthorZhang, L
AffiliationChinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China
Recommended Citation
GB/T 7714
Zhang, L,Zhao, LZ,Zhang, JB,et al. Anodic electrocrystallization of BaKPbO and BaKPbBiO from molten salt[J]. ACTA PHYSICO-CHIMICA SINICA,1999,15(11):1049-1052.
APA Zhang, L,Zhao, LZ,Zhang, JB,Xu, CY,&Liu, SH.(1999).Anodic electrocrystallization of BaKPbO and BaKPbBiO from molten salt.ACTA PHYSICO-CHIMICA SINICA,15(11),1049-1052.
MLA Zhang, L,et al."Anodic electrocrystallization of BaKPbO and BaKPbBiO from molten salt".ACTA PHYSICO-CHIMICA SINICA 15.11(1999):1049-1052.
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