ICCAS OpenIR
Influence of intramolecular substitution reaction of square planar carbonyl rhodium (I) cationic complex on its stability
Jiang, H; Pan, PL; Yuan, GQ
1999-07-01
Source PublicationCHINESE SCIENCE BULLETIN
ISSN1001-6538
Volume44Issue:13Pages:1195-1198
AbstractTwo cis-dicarbonyl rhodium complexes containing uncoordinated donors have been synthesized, and their IR and XPS data and the influence of their intramolecular substitution reaction on their stabilities have been reported. The intramolecular substitution reaction is reversible. Under the condition of heating and without the protection of CO, the uncoordinated donors substitute the terminal carbonyls on the rhodium to form tetradentated complex. So the rhodium complex will not decompose for the drop of the terminal carbonyls and its stability is enhanced. In atmosphere of CO, it recovers to bidentate complex.
KeywordRhodium Complex Intramolecular Substitution Stability
Indexed BySCI
Language英语
WOS IDWOS:000082955000009
PublisherSCIENCE PRESS
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Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/75486
Collection中国科学院化学研究所
Corresponding AuthorYuan, GQ
AffiliationChinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China
Recommended Citation
GB/T 7714
Jiang, H,Pan, PL,Yuan, GQ. Influence of intramolecular substitution reaction of square planar carbonyl rhodium (I) cationic complex on its stability[J]. CHINESE SCIENCE BULLETIN,1999,44(13):1195-1198.
APA Jiang, H,Pan, PL,&Yuan, GQ.(1999).Influence of intramolecular substitution reaction of square planar carbonyl rhodium (I) cationic complex on its stability.CHINESE SCIENCE BULLETIN,44(13),1195-1198.
MLA Jiang, H,et al."Influence of intramolecular substitution reaction of square planar carbonyl rhodium (I) cationic complex on its stability".CHINESE SCIENCE BULLETIN 44.13(1999):1195-1198.
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