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Preparation and properties of (BEDT-TTF)(2)Br(center dot)3H(2)O salt
Zhang, QC; Wu, PJ; Jiang, KJ; Ding, RS; Wang, YQ; Zhu, DB
1999-02-01
Source PublicationCHINESE CHEMICAL LETTERS
ISSN1001-8417
Volume10Issue:2Pages:179-182
AbstractElectrochemical oxidation of BEDT-TTF (bis (ethylenedithio) tetrathiafulvalene) in chloroform/carbon disulfide (3:1) in the presence of Bu4NBr as a supporting electrolyte at low current density results in the (BEDT-TTF)(2)Br3H(2)O crystal. Its composition has been established by chemical analysis (Br, C, H. S), XPS and IR. The temperature dependence of the resistance has been studied down to 26K at ambient pressure. This material has weakly metallic behavior above 230K, and becomes a semiconductor below this temperature. The structure of the complex is also described.
KeywordOrganic Conductor Charge Transfer Complex Preparation Electrical Properties Structure
Indexed BySCI
Language英语
WOS IDWOS:000081029500033
PublisherCHINESE CHEMICAL SOCIETY
Citation statistics
Cited Times:1[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/75474
Collection中国科学院化学研究所
AffiliationChinese Acad Sci, Inst Chem, Organ Solid Lab, Beijing 100080, Peoples R China
Recommended Citation
GB/T 7714
Zhang, QC,Wu, PJ,Jiang, KJ,et al. Preparation and properties of (BEDT-TTF)(2)Br(center dot)3H(2)O salt[J]. CHINESE CHEMICAL LETTERS,1999,10(2):179-182.
APA Zhang, QC,Wu, PJ,Jiang, KJ,Ding, RS,Wang, YQ,&Zhu, DB.(1999).Preparation and properties of (BEDT-TTF)(2)Br(center dot)3H(2)O salt.CHINESE CHEMICAL LETTERS,10(2),179-182.
MLA Zhang, QC,et al."Preparation and properties of (BEDT-TTF)(2)Br(center dot)3H(2)O salt".CHINESE CHEMICAL LETTERS 10.2(1999):179-182.
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