Knowledge Management System Of Institute of Chemistry，CAS
| Improvement on stability of square planar rhodium (I) complexes for carbonylation of methanol to acetic acid | |
| Jiang, H; Pan, PL; Yuan, GQ; Chen, XZ | |
| 1999-06-01 | |
| Source Publication | SCIENCE IN CHINA SERIES B-CHEMISTRY
 |
| ISSN | 1006-9291 |
| Volume | 42Issue:3Pages:311-315 |
| Abstract | A series of square planar cis-dicarbonyl polymer coordinated rhodium complexes with uncoordinated donors near the central rhodium atoms for carbonylation of methanol to acetic acid are reported. Data of IR, XPS and thermal analysis show that these complexes are very stable. The intramolecular substitution reaction is proposed for their high stability. These complexes show excellent catalytic activity, selectivity and less erosion to the equipment for the methanol carbonylation to acetic acid. The distillation process may be used instead of flash vaporization in the manufacture of acetic acid, which reduces the investment on the equipment. |
| Keyword | Rhodium Complex Square Planar Intramolecular Substitution |
| Indexed By | SCI |
| Language | 英语 |
| WOS ID | WOS:000080893100012 |
| Publisher | SCIENCE PRESS |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.iccas.ac.cn/handle/121111/75372 |
| Collection | 中国科学院化学研究所 |
| Corresponding Author | Yuan, GQ |
| Affiliation | 1.Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China 2.Hong Kong Polytech Univ, Dept Appl Biol & Chem Technol, Hong Kong, Peoples R China |
| Recommended Citation GB/T 7714 | Jiang, H,Pan, PL,Yuan, GQ,et al. Improvement on stability of square planar rhodium (I) complexes for carbonylation of methanol to acetic acid[J]. SCIENCE IN CHINA SERIES B-CHEMISTRY,1999,42(3):311-315. |
| APA | Jiang, H,Pan, PL,Yuan, GQ,&Chen, XZ.(1999).Improvement on stability of square planar rhodium (I) complexes for carbonylation of methanol to acetic acid.SCIENCE IN CHINA SERIES B-CHEMISTRY,42(3),311-315. |
| MLA | Jiang, H,et al."Improvement on stability of square planar rhodium (I) complexes for carbonylation of methanol to acetic acid".SCIENCE IN CHINA SERIES B-CHEMISTRY 42.3(1999):311-315. |
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