ICCAS OpenIR
Improvement on stability of square planar rhodium (I) complexes for carbonylation of methanol to acetic acid
Jiang, H; Pan, PL; Yuan, GQ; Chen, XZ
1999-06-01
Source PublicationSCIENCE IN CHINA SERIES B-CHEMISTRY
ISSN1006-9291
Volume42Issue:3Pages:311-315
AbstractA series of square planar cis-dicarbonyl polymer coordinated rhodium complexes with uncoordinated donors near the central rhodium atoms for carbonylation of methanol to acetic acid are reported. Data of IR, XPS and thermal analysis show that these complexes are very stable. The intramolecular substitution reaction is proposed for their high stability. These complexes show excellent catalytic activity, selectivity and less erosion to the equipment for the methanol carbonylation to acetic acid. The distillation process may be used instead of flash vaporization in the manufacture of acetic acid, which reduces the investment on the equipment.
KeywordRhodium Complex Square Planar Intramolecular Substitution
Indexed BySCI
Language英语
WOS IDWOS:000080893100012
PublisherSCIENCE PRESS
Citation statistics
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/75372
Collection中国科学院化学研究所
Corresponding AuthorYuan, GQ
Affiliation1.Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China
2.Hong Kong Polytech Univ, Dept Appl Biol & Chem Technol, Hong Kong, Peoples R China
Recommended Citation
GB/T 7714
Jiang, H,Pan, PL,Yuan, GQ,et al. Improvement on stability of square planar rhodium (I) complexes for carbonylation of methanol to acetic acid[J]. SCIENCE IN CHINA SERIES B-CHEMISTRY,1999,42(3):311-315.
APA Jiang, H,Pan, PL,Yuan, GQ,&Chen, XZ.(1999).Improvement on stability of square planar rhodium (I) complexes for carbonylation of methanol to acetic acid.SCIENCE IN CHINA SERIES B-CHEMISTRY,42(3),311-315.
MLA Jiang, H,et al."Improvement on stability of square planar rhodium (I) complexes for carbonylation of methanol to acetic acid".SCIENCE IN CHINA SERIES B-CHEMISTRY 42.3(1999):311-315.
Files in This Item:
There are no files associated with this item.
Related Services
Recommend this item
Bookmark
Usage statistics
Export to Endnote
Google Scholar
Similar articles in Google Scholar
[Jiang, H]'s Articles
[Pan, PL]'s Articles
[Yuan, GQ]'s Articles
Baidu academic
Similar articles in Baidu academic
[Jiang, H]'s Articles
[Pan, PL]'s Articles
[Yuan, GQ]'s Articles
Bing Scholar
Similar articles in Bing Scholar
[Jiang, H]'s Articles
[Pan, PL]'s Articles
[Yuan, GQ]'s Articles
Terms of Use
No data!
Social Bookmark/Share
All comments (0)
No comment.
 

Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.