ICCAS OpenIR
Synthesis and crystal structure of [EDA][Ni(dmit)(2)](3)
Sun, SQ; Wu, PJ; Zhu, DB; Xu, XY
1999
Source PublicationCHINESE JOURNAL OF STRUCTURAL CHEMISTRY
ISSN0254-5861
Volume18Issue:2Pages:79-83
AbstractThe crystal structure of the compound [EDA] [Ni(dmit)(2)](3) (EDA = 2-diethylamino-1,3-dithioanylium; dmit = 1,3-dithiole-2-thione-4,5-dithiolate) C25H14NNi3S32, has been determined by single crystal X-ray diffraction at 300K. The crystal is triclinic with space group P (1) over bar, a = 11. 252, b = 12.192(2), c = 20.055(6) Angstrom, alpha = 108.127(2), beta = 106.281(8), gamma = 90.005(9)degrees; V = 2498.3(3) Angstrom(3), Z = 2, M-r = 1530.38, D-c = 2.03(2) g/cm(3). Final R and R-w values were 0.0603 and 0.0104, respectively. The structure consists of thick layers of stacked Ni(dmit)(2) entities separated by EDA cations. This salt shows semiconducting behaviour with room temperature conductivity of 0.2 Scm(-1) and activation energy of 0.11 eV.
KeywordElectrocrystallization Crystal Structure Charge Transfer Salt
Indexed BySCI
Language英语
WOS IDWOS:000079407200001
PublisherCHINESE JOURNAL STRUCTURAL CHEMISTRY
Citation statistics
Cited Times:3[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/75244
Collection中国科学院化学研究所
Corresponding AuthorSun, SQ
Affiliation1.Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China
2.Capital Univ Med Sci, Basic Sch Med Sci, Beijing 100054, Peoples R China
Recommended Citation
GB/T 7714
Sun, SQ,Wu, PJ,Zhu, DB,et al. Synthesis and crystal structure of [EDA][Ni(dmit)(2)](3)[J]. CHINESE JOURNAL OF STRUCTURAL CHEMISTRY,1999,18(2):79-83.
APA Sun, SQ,Wu, PJ,Zhu, DB,&Xu, XY.(1999).Synthesis and crystal structure of [EDA][Ni(dmit)(2)](3).CHINESE JOURNAL OF STRUCTURAL CHEMISTRY,18(2),79-83.
MLA Sun, SQ,et al."Synthesis and crystal structure of [EDA][Ni(dmit)(2)](3)".CHINESE JOURNAL OF STRUCTURAL CHEMISTRY 18.2(1999):79-83.
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