ICCAS OpenIR
Nickel-catalyzed carbonylation of methyl acetate to acetic anhydride
Gong, JF; Fan, QH; Jiang, DZ
1999-11-17
Source PublicationJOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL
ISSN1381-1169
Volume147Issue:1-2Pages:113-124
AbstractLiquid phase carbonylation of methyl acetate to acetic anhydride using nickel catalyst with methyl iodide promoter is reported. Effect of different catalyst precursors, total reaction pressure, hydrogen partial pressure, temperature, catalyst, lithium acetate and methyl iodide concentration, a variety of ligands on the activity and selectivity of nickel catalyst has been investigated. Additionally, FT-IR spectra of the reaction solution were studied and possible side reactions in the carbonylation were examined. Based on these observations, a proposed mechanism for the homogeneous nickel-catalyzed carbonylation of methyl acetate was discussed. (C) 1999 Elsevier Science B.V. All rights reserved.
KeywordNickel Catalyst Carbonylation Acetic Anhydride Ligand Mechanism
Indexed ByISTP ; SCI
Language英语
WOS IDWOS:000083978400017
PublisherELSEVIER SCIENCE BV
Citation statistics
Cited Times:4[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/74848
Collection中国科学院化学研究所
Corresponding AuthorJiang, DZ
AffiliationChinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China
Recommended Citation
GB/T 7714
Gong, JF,Fan, QH,Jiang, DZ. Nickel-catalyzed carbonylation of methyl acetate to acetic anhydride[J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL,1999,147(1-2):113-124.
APA Gong, JF,Fan, QH,&Jiang, DZ.(1999).Nickel-catalyzed carbonylation of methyl acetate to acetic anhydride.JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL,147(1-2),113-124.
MLA Gong, JF,et al."Nickel-catalyzed carbonylation of methyl acetate to acetic anhydride".JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL 147.1-2(1999):113-124.
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