ICCAS OpenIR
Catalytic behavior of a Wool-Pd complex in asymmetric hydrogenation of diacetone alcohol and 3-methyl-2-butanone
Yin, MY; Yuan, GL; Huang, MY; Jiang, YY
1999-11-17
Source PublicationJOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL
ISSN1381-1169
Volume147Issue:1-2Pages:89-92
AbstractA Wool-Pd complex has been found to be able to catalyze the asymmetric hydrogenation of diacetone alcohol to (R)-2-methyl-2,4-pentanediol acid 3-methyl-2-butanone to (R)-3-methyl-2-butanol at 30 degrees C and under 1 atm H-2. The optical yields were greatly affected by Pd content in Wool-Pd complex. When a proper Pd content was selected, (R)-2-methyl-2,4-pentanediol and (R)-3-methyl-2-butanol could be obtained in 73 and 100% optical yield, respectively. This chiral natural biopolymer-Pd complex catalyst was easy to prepare and could be reused without appreciable change in optical catalytic activity. (C) 1999 Elsevier Science B.V. All rights reserved.
KeywordWool-pd Complex Diacetone Alcohol Asymmetric Hydrogenation
Indexed ByISTP ; SCI
Language英语
WOS IDWOS:000083978400013
PublisherELSEVIER SCIENCE BV
Citation statistics
Cited Times:22[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/74816
Collection中国科学院化学研究所
Corresponding AuthorYuan, GL
AffiliationChinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China
Recommended Citation
GB/T 7714
Yin, MY,Yuan, GL,Huang, MY,et al. Catalytic behavior of a Wool-Pd complex in asymmetric hydrogenation of diacetone alcohol and 3-methyl-2-butanone[J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL,1999,147(1-2):89-92.
APA Yin, MY,Yuan, GL,Huang, MY,&Jiang, YY.(1999).Catalytic behavior of a Wool-Pd complex in asymmetric hydrogenation of diacetone alcohol and 3-methyl-2-butanone.JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL,147(1-2),89-92.
MLA Yin, MY,et al."Catalytic behavior of a Wool-Pd complex in asymmetric hydrogenation of diacetone alcohol and 3-methyl-2-butanone".JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL 147.1-2(1999):89-92.
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