ICCAS OpenIR
A model for correlating the solubility of solids in supercritical CO2
Zhong, MH; Han, BX; Ke, J; Yan, HK; Peng, DY
1998-05-01
Source PublicationFLUID PHASE EQUILIBRIA
ISSN0378-3812
Volume146Issue:1-2Pages:93-102
AbstractA model for correlating the phase equilibria of solid-supercritical fluid (SCF) systems has been developed. The model is based on the fact that the free solute molecules, the solvent molecules, and the solute-solvent clusters in such a solid-SCF system are in chemical equilibrium. The local density of the solvent surrounding a solute is used as one of the parameters in the model. The validity of the model is verified by correlation of the phase equilibrium data of supercritical CO2-solid systems reported in the literature. Using the solubility data, the model can be used to estimate the local density and the average number of the solvent molecules in the clusters. (C) 1998 Elsevier Science B.V. All rights reserved.
KeywordSupercritical Fluid Solid-fluid Equilibria Cluster
Indexed ByISTP ; SCI
Language英语
WOS IDWOS:000074478100008
PublisherELSEVIER SCIENCE BV
Citation statistics
Cited Times:26[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/74802
Collection中国科学院化学研究所
Corresponding AuthorHan, BX
Affiliation1.Acad Sinica, Inst Chem, Beijing 100080, Peoples R China
2.Univ Saskatchewan, Dept Chem Engn, Saskatoon, SK S7N 5C9, Canada
Recommended Citation
GB/T 7714
Zhong, MH,Han, BX,Ke, J,et al. A model for correlating the solubility of solids in supercritical CO2[J]. FLUID PHASE EQUILIBRIA,1998,146(1-2):93-102.
APA Zhong, MH,Han, BX,Ke, J,Yan, HK,&Peng, DY.(1998).A model for correlating the solubility of solids in supercritical CO2.FLUID PHASE EQUILIBRIA,146(1-2),93-102.
MLA Zhong, MH,et al."A model for correlating the solubility of solids in supercritical CO2".FLUID PHASE EQUILIBRIA 146.1-2(1998):93-102.
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