ICCAS OpenIR
Structural studies on host plus guest recognition sensory systems
Yang, LJ; Feng, XZ; Lee, I; Bai, CL
1998-07-01
Source PublicationJOURNAL OF INCLUSION PHENOMENA AND MOLECULAR RECOGNITION IN CHEMISTRY
ISSN0923-0750
Volume31Issue:3Pages:197-204
AbstractRhodamine B-ethylenediamine-beta-cyclodextrins (RhB-beta-CDen) and rhodamine B-beta-cyclodextrins (RhB-beta-CD) can form inclusive complexes with many guest molecules; a reaction which can be used as a nucleic acid probe. In this paper, the most stable conformations of RhB-beta-CDen and RhB-beta-CD have been determined by fluorescence experiments and analyzed by molecular modeling simulation. The interaction between RhB-beta-CDen and two guest molecules, I-borneol and cyclohexanol, has also been investigated. The results showed that RhB-beta-CDen has a stronger interaction with l-borneol than with cyclohexanol. Borneol could push the three aromatic-rings of rhodamine B out of the CD cavity, while the cyclohexanol could not. The interactive sites of host and guest are also presented.
KeywordRhb-beta-cden Rhb-beta-cd Recognition Host + Guest Cyclohexanol Molecular Dynamics 1-borneol
Indexed BySCI
Language英语
WOS IDWOS:000075120500002
PublisherKLUWER ACADEMIC PUBL
Citation statistics
Cited Times:1[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/74768
Collection中国科学院化学研究所
Corresponding AuthorBai, CL
AffiliationChinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China
Recommended Citation
GB/T 7714
Yang, LJ,Feng, XZ,Lee, I,et al. Structural studies on host plus guest recognition sensory systems[J]. JOURNAL OF INCLUSION PHENOMENA AND MOLECULAR RECOGNITION IN CHEMISTRY,1998,31(3):197-204.
APA Yang, LJ,Feng, XZ,Lee, I,&Bai, CL.(1998).Structural studies on host plus guest recognition sensory systems.JOURNAL OF INCLUSION PHENOMENA AND MOLECULAR RECOGNITION IN CHEMISTRY,31(3),197-204.
MLA Yang, LJ,et al."Structural studies on host plus guest recognition sensory systems".JOURNAL OF INCLUSION PHENOMENA AND MOLECULAR RECOGNITION IN CHEMISTRY 31.3(1998):197-204.
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