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Synthesis of the first mono(cyclopentadienyl)lanthanide Schiff base complex bearing C-2-symmetric tetradentate ligand: crystal structure of [(eta(5)-C5H5)Yb(mu-OC20H20N2O)](2)(mu-THF)(THF)
Liu, QC; Ding, MX
1998-02-25
Source PublicationJOURNAL OF ORGANOMETALLIC CHEMISTRY
ISSN0022-328X
Volume553Issue:1-2Pages:179-181
AbstractReaction of YbCl3 with 3 equimolar CpNa (Cp = cyclopentadienide) in THF, followed by treatment with trans-(+/-)-N,N'-bis(salicylidene)-1,2-cyclohexanediamine led to the isolation of first mono(cyclopentadienyl) lanthanide Schiff base complex, [(eta(5)-C5H5)Yb(mu-OC20H20N2O)](2) (mu-THF)(THF) (1). The molecular structure of 1 shows that it is a dimer in which the two [(eta(5)-C5H5)Yb(mu-OC20H20N2O)] units connecting via a bridging THF oxygen and two bridging oxygen atoms from Schiff base ligands. (C) 1998 Elsevier Science S.A.
KeywordOrganoytterbium Complex C-2-symmetry Schiff Base Crystal Structure
Indexed BySCI
Language英语
WOS IDWOS:000073764600023
PublisherELSEVIER SCIENCE SA
Citation statistics
Cited Times:24[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/74742
Collection中国科学院化学研究所
Corresponding AuthorDing, MX
AffiliationChinese Acad Sci, Changchun Inst Appl Chem, PCLCC, Changchun 130022, Peoples R China
Recommended Citation
GB/T 7714
Liu, QC,Ding, MX. Synthesis of the first mono(cyclopentadienyl)lanthanide Schiff base complex bearing C-2-symmetric tetradentate ligand: crystal structure of [(eta(5)-C5H5)Yb(mu-OC20H20N2O)](2)(mu-THF)(THF)[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY,1998,553(1-2):179-181.
APA Liu, QC,&Ding, MX.(1998).Synthesis of the first mono(cyclopentadienyl)lanthanide Schiff base complex bearing C-2-symmetric tetradentate ligand: crystal structure of [(eta(5)-C5H5)Yb(mu-OC20H20N2O)](2)(mu-THF)(THF).JOURNAL OF ORGANOMETALLIC CHEMISTRY,553(1-2),179-181.
MLA Liu, QC,et al."Synthesis of the first mono(cyclopentadienyl)lanthanide Schiff base complex bearing C-2-symmetric tetradentate ligand: crystal structure of [(eta(5)-C5H5)Yb(mu-OC20H20N2O)](2)(mu-THF)(THF)".JOURNAL OF ORGANOMETALLIC CHEMISTRY 553.1-2(1998):179-181.
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