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Synthesis, electrical properties of [Ni(dmit)(2)](-) complexes and X-ray crystal structure of [EDA][Ni(dmit)(2)] (dmit equals 1,3-dithiol-2-thione-4,5-dithiolate)
Sun, SQ; Wu, PJ; Zhu, DB; Ma, ZS; Shi, NC
1998-02-03
Source PublicationINORGANICA CHIMICA ACTA
ISSN0020-1693
Volume268Issue:1Pages:103-107
AbstractThe complexes [MDC] [Ni(dmit)(2)] (1) (MDC = dimethylamino-dithioImethyl carbonium), [MDA] [Ni(dmit)(2)] (2) (MDA = 2-dimethylamino-1,3-dithiolanylium), [PDA] [Ni(dmit)(2)] (3) (PDA = 2-cyclopentaamino-1,3-dithiolanylium) and [EDA] [Ni(dmit)(2)] (4) (EDA = 2-diethylamino-1,3-dithiolanylium) have been prepared. All these complexes behave as semiconductors. However, the conductivities increased by 10(3)-10(5) times when they were doped with iodine. A single X-ray crystal structure analysis of complex 3 reveals that there are short S ... S contacts between cation and anion complexes. The triclinic system, space group P (1) over bar, has cell dimensions a = 10.113(3), b = 13.612(4), c = 9.151(3) Angstrom, alpha = 69.57(3), beta = 77.22(3), gamma = 82.54(3)degrees and Z = 2. Full-matrix least-squares refinement, based on 2801 reflections converged at R = 0.062. (C) 1998 Elsevier Science S.A.
KeywordNickel Complexes Dithiolate Complexes Electrical Conductivity Crystal Structures Synthesis
Indexed BySCI
Language英语
WOS IDWOS:000071095000014
PublisherELSEVIER SCIENCE SA
Citation statistics
Cited Times:9[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/74708
Collection中国科学院化学研究所
Corresponding AuthorZhu, DB
Affiliation1.Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China
2.China Univ Geosci, Xray Lab, Beijing 100083, Peoples R China
Recommended Citation
GB/T 7714
Sun, SQ,Wu, PJ,Zhu, DB,et al. Synthesis, electrical properties of [Ni(dmit)(2)](-) complexes and X-ray crystal structure of [EDA][Ni(dmit)(2)] (dmit equals 1,3-dithiol-2-thione-4,5-dithiolate)[J]. INORGANICA CHIMICA ACTA,1998,268(1):103-107.
APA Sun, SQ,Wu, PJ,Zhu, DB,Ma, ZS,&Shi, NC.(1998).Synthesis, electrical properties of [Ni(dmit)(2)](-) complexes and X-ray crystal structure of [EDA][Ni(dmit)(2)] (dmit equals 1,3-dithiol-2-thione-4,5-dithiolate).INORGANICA CHIMICA ACTA,268(1),103-107.
MLA Sun, SQ,et al."Synthesis, electrical properties of [Ni(dmit)(2)](-) complexes and X-ray crystal structure of [EDA][Ni(dmit)(2)] (dmit equals 1,3-dithiol-2-thione-4,5-dithiolate)".INORGANICA CHIMICA ACTA 268.1(1998):103-107.
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