ICCAS OpenIR
Vibrational energy transfer from highly excited state CO to C2H2
Wang, BS; Guo, JZ; Gu, YS
1998-04-01
Source PublicationACTA PHYSICO-CHIMICA SINICA
ISSN1000-6818
Volume14Issue:4Pages:327-331
AbstractThe energy transfer process of highly vibrational states of CO with C2H2 has been studied by the Time-resolved Fourier Transform Infrared Emission Spectroscopy. The vibrational population of CO (upsilon=1-3) were obtained by the simulations of the IR emission spectra. Differentiation method was used to calculate the quenching rate constants of CO(upsilon=1-3) which are 2.0+/-0.1, 6.0+/-0.2 and 9.4+/-0.8 (10(-13) cm(3).molecule(-1).S-1), respectively. The west possible energy transfer channel is the transfer of CO(upsilon) to C2H2 (upsilon(2)). Dimer complexes may be formed in the collisional process. The equilibrium structures and lifetime of the complexes were estimated by ab initio computation and V-V/R theory.
KeywordTime-resolved Ir Spectra Highly Vibrational Excited State V-v Energy Transfer
DOI10.3866/PKU.WHXB19980408
Indexed BySCI
Language英语
WOS IDWOS:000074858600008
PublisherPEKING UNIV PRESS
Citation statistics
Cited Times:5[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/74598
Collection中国科学院化学研究所
Corresponding AuthorGu, YS
Affiliation1.Shandong Univ, Dept Chem, Jinan 250100, Peoples R China
2.Chinese Acad Sci, Inst Chem, State Key Lab Mol React Dynam, Beijing 100080, Peoples R China
Recommended Citation
GB/T 7714
Wang, BS,Guo, JZ,Gu, YS. Vibrational energy transfer from highly excited state CO to C2H2[J]. ACTA PHYSICO-CHIMICA SINICA,1998,14(4):327-331.
APA Wang, BS,Guo, JZ,&Gu, YS.(1998).Vibrational energy transfer from highly excited state CO to C2H2.ACTA PHYSICO-CHIMICA SINICA,14(4),327-331.
MLA Wang, BS,et al."Vibrational energy transfer from highly excited state CO to C2H2".ACTA PHYSICO-CHIMICA SINICA 14.4(1998):327-331.
Files in This Item:
There are no files associated with this item.
Related Services
Recommend this item
Bookmark
Usage statistics
Export to Endnote
Google Scholar
Similar articles in Google Scholar
[Wang, BS]'s Articles
[Guo, JZ]'s Articles
[Gu, YS]'s Articles
Baidu academic
Similar articles in Baidu academic
[Wang, BS]'s Articles
[Guo, JZ]'s Articles
[Gu, YS]'s Articles
Bing Scholar
Similar articles in Bing Scholar
[Wang, BS]'s Articles
[Guo, JZ]'s Articles
[Gu, YS]'s Articles
Terms of Use
No data!
Social Bookmark/Share
All comments (0)
No comment.
 

Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.