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| New bisdithiolene metal complex of the 2-thioxo-1,3-dithiole-4,5-dithiolato(dmit) ligand. Preparation, structure and physical properties | |
| Zhang, QC; Wu, PJ; Sun, SQ; Zhu, DB; Xong, M; Ma, ZS; Shi, NC | |
| 1998-12-04 | |
| Source Publication | SYNTHETIC METALS
 |
| ISSN | 0379-6779 |
| Volume | 98Issue:2Pages:103-106 |
| Abstract | The complex HMEDA[Ni(dmit)(2)](2)I (HMEDA = Hexamethylethylenediammonium) has been prepared. A single X-ray crystal structure analysis reveals that there are short S ... S contacts between Ni(dmit)(2) dimmers. The monoclinic system, space group p2/n, has cell dimensions: a = 11.710(3) Angstrom, b = 22.559(5) Angstrom, c = 7.374(2) Angstrom, beta = 93.000(3)(0), V = 1945.3(8) Angstrom(3), z = 4. Full-matrix least-squares refinement, based on 2989 reflections converged at R = 0.0686. The conductivity of this salt at room temperature is 0.1 S cm(-1) and it shows semiconducting behavior from 20 to 300 K. (C) 1998 Elsevier Science S.A. All rights reserved. |
| Keyword | Nickel Complexes Dithiolate Complexes Electrical Conductivity Crystal Structure Synthesis |
| Indexed By | SCI |
| Language | 英语 |
| WOS ID | WOS:000077636400004 |
| Publisher | ELSEVIER SCIENCE SA |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.iccas.ac.cn/handle/121111/74546 |
| Collection | 中国科学院化学研究所 |
| Corresponding Author | Zhu, DB |
| Affiliation | 1.Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China 2.China Univ Geosci, Xray Lab, Beijing 100083, Peoples R China |
| Recommended Citation GB/T 7714 | Zhang, QC,Wu, PJ,Sun, SQ,et al. New bisdithiolene metal complex of the 2-thioxo-1,3-dithiole-4,5-dithiolato(dmit) ligand. Preparation, structure and physical properties[J]. SYNTHETIC METALS,1998,98(2):103-106. |
| APA | Zhang, QC.,Wu, PJ.,Sun, SQ.,Zhu, DB.,Xong, M.,...&Shi, NC.(1998).New bisdithiolene metal complex of the 2-thioxo-1,3-dithiole-4,5-dithiolato(dmit) ligand. Preparation, structure and physical properties.SYNTHETIC METALS,98(2),103-106. |
| MLA | Zhang, QC,et al."New bisdithiolene metal complex of the 2-thioxo-1,3-dithiole-4,5-dithiolato(dmit) ligand. Preparation, structure and physical properties".SYNTHETIC METALS 98.2(1998):103-106. |
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