ICCAS OpenIR
HeI photoelectron spectroscopic study of the electronic structure of SSF2 and FSSF compounds
Cao, XY; Qiao, CH; Wang, DX
1998-07-03
Source PublicationCHEMICAL PHYSICS LETTERS
ISSN0009-2614
Volume290Issue:4-6Pages:405-408
AbstractHeI photoelectron (PE) spectra are re-recorded for SSF2 and FSSF. The assignment of bands has been made with the aid of band shapes, band intensities and ab initio calculations. In the PE spectrum of SSF2, two sharp peaks at 10.48 and 11.22 eV are considered to result from through-space interaction of lone-pair orbitals in the two S atoms and two sharp peaks at 12.50 and 12.90 eV from through-space interaction of lone-pair orbitals in the two F atoms. The larger splitting of the S atoms can be attributed to the larger 3p orbital of S. The lack of sharp peaks in the PE spectrum of FSSF shows that there is no orbital which embodies the character of a lone-pair. So the PE spectra of SSF2 and FSSF are examples embodying through-space interaction of lone-pair orbitals. (C) 1998 Elsevier Science B.V. All rights reserved.
Indexed BySCI
Language英语
WOS IDWOS:000074715000017
PublisherELSEVIER SCIENCE BV
Citation statistics
Cited Times:11[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/74530
Collection中国科学院化学研究所
Corresponding AuthorWang, DX
AffiliationChinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China
Recommended Citation
GB/T 7714
Cao, XY,Qiao, CH,Wang, DX. HeI photoelectron spectroscopic study of the electronic structure of SSF2 and FSSF compounds[J]. CHEMICAL PHYSICS LETTERS,1998,290(4-6):405-408.
APA Cao, XY,Qiao, CH,&Wang, DX.(1998).HeI photoelectron spectroscopic study of the electronic structure of SSF2 and FSSF compounds.CHEMICAL PHYSICS LETTERS,290(4-6),405-408.
MLA Cao, XY,et al."HeI photoelectron spectroscopic study of the electronic structure of SSF2 and FSSF compounds".CHEMICAL PHYSICS LETTERS 290.4-6(1998):405-408.
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