ICCAS OpenIR
Intramolecular reaction of polymer coordinated cationic rhodium complex
Peng, WQ; Zhu, CC; Yuan, GQ
1998-02-01
Source PublicationSCIENCE IN CHINA SERIES B-CHEMISTRY
ISSN1006-9291
Volume41Issue:1Pages:14-20
AbstractA square planar rhodium complex from the copolymer of 2-pyridyl ethylene and other low-molecular weight rhodium complexes with similar structure are reported. The experimental results of XPS and IR spectroscopy indicated that the weak N-->Rh coordination bond can easily replace the strong Rh-C back donation bond with the elevation of temperature due to the steric effect. The terminal carbonyl group in the complex will be substituted to form tridentate and then tetradentate complexes. This is a reversible process. When they are in the atmosphere of CO, tridentate and bidentate complexes will form. These experimental results provide the theoretical reason why the catalytic activities from the polymer coordinated rhodium complex is superior to that of other rhodium complexes.
KeywordComplex Square Plane Intramolecular Substitution
Indexed BySCI
Language英语
WOS IDWOS:000071615300002
PublisherSCIENCE PRESS
Citation statistics
Cited Times:2[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/74512
Collection中国科学院化学研究所
Corresponding AuthorYuan, GQ
AffiliationChinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China
Recommended Citation
GB/T 7714
Peng, WQ,Zhu, CC,Yuan, GQ. Intramolecular reaction of polymer coordinated cationic rhodium complex[J]. SCIENCE IN CHINA SERIES B-CHEMISTRY,1998,41(1):14-20.
APA Peng, WQ,Zhu, CC,&Yuan, GQ.(1998).Intramolecular reaction of polymer coordinated cationic rhodium complex.SCIENCE IN CHINA SERIES B-CHEMISTRY,41(1),14-20.
MLA Peng, WQ,et al."Intramolecular reaction of polymer coordinated cationic rhodium complex".SCIENCE IN CHINA SERIES B-CHEMISTRY 41.1(1998):14-20.
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