ICCAS OpenIR
The hydro silylation reaction of ladderlike polyvinylsilsesquioxane with 1,1,3,3-tetramethyldisiloxane
Cao, XY; Xu, H; Wang, LT; Li, Z; Cao, M; Xie, P; Zhang, RB; Zhu, CF; Wang, C
1998
Source PublicationCHINESE JOURNAL OF POLYMER SCIENCE
ISSN0256-7679
Volume16Issue:3Pages:226-233
AbstractThe hydrosilylation reaction of ladderlike polyvinylsilsesquioxane (Vi-T) with 1, 1, 3, 3-tetramethyldisiloxane (H-MM) catalyzed by dicyclopentadienyl-dichloroplatinium (Cp2PtCl2) was carried out well in tetrahydrofuran (THF) to produce a soluble white solid. This product was characterized by IR, H-1-NMR, C-13-NMR, Si-29-NMR, DSC, X-ray diffraction method, gel permeation chromatography (GPC), vapour pressure osmometry (VPO), atomic force microscopy (AFM) and molecular simulation. These results prove that the product contains nanoscale tubular structure.
KeywordHydrosilylation Polyorganosiloxane Tubular Structure Characterisation
Indexed BySCI
Language英语
WOS IDWOS:000075584800005
PublisherSCIENCE PRESS
Citation statistics
Cited Times:8[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/74476
Collection中国科学院化学研究所
Affiliation1.Chinese Acad Sci, Inst Chem, PCLCC, Polymer Chem Lab, Beijing 100080, Peoples R China
2.Chinese Acad Sci, Inst Chem, PCLCC, China Petr Chem Corp, Beijing 100080, Peoples R China
3.Chinese Acad Sci, Youth Lab Nanosci & Technol, Beijing 100080, Peoples R China
Recommended Citation
GB/T 7714
Cao, XY,Xu, H,Wang, LT,et al. The hydro silylation reaction of ladderlike polyvinylsilsesquioxane with 1,1,3,3-tetramethyldisiloxane[J]. CHINESE JOURNAL OF POLYMER SCIENCE,1998,16(3):226-233.
APA Cao, XY.,Xu, H.,Wang, LT.,Li, Z.,Cao, M.,...&Wang, C.(1998).The hydro silylation reaction of ladderlike polyvinylsilsesquioxane with 1,1,3,3-tetramethyldisiloxane.CHINESE JOURNAL OF POLYMER SCIENCE,16(3),226-233.
MLA Cao, XY,et al."The hydro silylation reaction of ladderlike polyvinylsilsesquioxane with 1,1,3,3-tetramethyldisiloxane".CHINESE JOURNAL OF POLYMER SCIENCE 16.3(1998):226-233.
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