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Synthesis, crystal structure and electrical properties of [Pd(dmit)(2)](2-) and [Pd(dmit)(2)](0.5-) anion complexes with 2-dimethylamino-1,3-dithiolanylium as counter cation
Sun, SQ; Wu, PJ; Zhu, DB
1998-08-15
Source PublicationSYNTHETIC METALS
ISSN0379-6779
Volume96Issue:3Pages:199-204
AbstractThe synthesis, structural characterization and electrical conductivity measurement of [MDA](2)[Pd(dmit)(2)] (1) and [MDA] [Pd(dmit)(2)](2) (2) (MDA=2-dimethylamino-1,3-dithiolanylium, dmit = 1,3-dithiole-2-thione-4,5-dithiolate) are reported. Complex 1 consists of two Pd( dmit)2 anions and four MDA cations in the unit cell and the anions are separated by cations in the crystal; the conductivity is about 10(-7) S cm(-1). The structure of complex 2 is made of stacked Pd(dmit), dimers. The modes of intra- and inter-dimer molecular overlapping are both of slide-away types. Pd atoms deviate from planes formed by four Ligand S atoms 0.07 Angstrom apart to approach each other. Room-temperature conductivity is 10-70 S cm(-1). Temperature-dependent conductivity measurement of this compound indicated that it is a semiconductor with a low activation energy (0.043 eV). (C) 1998 Elsevier Science S.A. All rights reserved.
KeywordCarbonium Synthesis Electrical Properties Crystal Structures 1 3-dithiole-2-thione-4 5-dithiolate
Indexed BySCI
Language英语
WOS IDWOS:000075965800005
PublisherELSEVIER SCIENCE SA
Citation statistics
Cited Times:3[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/74430
Collection中国科学院化学研究所
Corresponding AuthorSun, SQ
AffiliationChinese Acad Sci, Inst Chem, Organ Solids Lab, Beijing 100080, Peoples R China
Recommended Citation
GB/T 7714
Sun, SQ,Wu, PJ,Zhu, DB. Synthesis, crystal structure and electrical properties of [Pd(dmit)(2)](2-) and [Pd(dmit)(2)](0.5-) anion complexes with 2-dimethylamino-1,3-dithiolanylium as counter cation[J]. SYNTHETIC METALS,1998,96(3):199-204.
APA Sun, SQ,Wu, PJ,&Zhu, DB.(1998).Synthesis, crystal structure and electrical properties of [Pd(dmit)(2)](2-) and [Pd(dmit)(2)](0.5-) anion complexes with 2-dimethylamino-1,3-dithiolanylium as counter cation.SYNTHETIC METALS,96(3),199-204.
MLA Sun, SQ,et al."Synthesis, crystal structure and electrical properties of [Pd(dmit)(2)](2-) and [Pd(dmit)(2)](0.5-) anion complexes with 2-dimethylamino-1,3-dithiolanylium as counter cation".SYNTHETIC METALS 96.3(1998):199-204.
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