ICCAS OpenIR
Asymmetric hydrogenation of alpha-ketoesters over finely dispersed polymer-stabilized platinum clusters
Zuo, XB; Liu, HF; Liu, MH
1998-04-02
Source PublicationTETRAHEDRON LETTERS
ISSN0040-4039
Volume39Issue:14Pages:1941-1944
AbstractFinely dispersed polyvinylpyrrolidone-stabilized platinum clusters (PVP-Pt) modified with cinchonidine catalyze the asymmetric hydrogenation of alpha-ketoesters, giving enantiomeric excesses in favour of R-(+)-methyl lactate up to 97.6%. The reaction is demonstrated to be structure insensitive and runs best over a tiny cluster with a mean size of 1.4 nm, which is quite different from conventional supported catalysts. (C) 1998 Elsevier Science Ltd. All rights reserved.
Indexed ByCCR ; SCI
Language英语
WOS IDWOS:000072599000027
PublisherPERGAMON-ELSEVIER SCIENCE LTD
Citation statistics
Cited Times:98[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/74252
Collection中国科学院化学研究所
Corresponding AuthorLiu, HF
Affiliation1.Chinese Acad Sci, Polymer Chem Lab, Beijing 100080, Peoples R China
2.Chinese Acad Sci, China Petrochem Corp, Inst Chem, Beijing 100080, Peoples R China
Recommended Citation
GB/T 7714
Zuo, XB,Liu, HF,Liu, MH. Asymmetric hydrogenation of alpha-ketoesters over finely dispersed polymer-stabilized platinum clusters[J]. TETRAHEDRON LETTERS,1998,39(14):1941-1944.
APA Zuo, XB,Liu, HF,&Liu, MH.(1998).Asymmetric hydrogenation of alpha-ketoesters over finely dispersed polymer-stabilized platinum clusters.TETRAHEDRON LETTERS,39(14),1941-1944.
MLA Zuo, XB,et al."Asymmetric hydrogenation of alpha-ketoesters over finely dispersed polymer-stabilized platinum clusters".TETRAHEDRON LETTERS 39.14(1998):1941-1944.
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