ICCAS OpenIR
Synthesis and characterization of water-soluble conducting copolymer poly(aniline-co-o-aminobenzenesulfonic acid)
Fan, JH; Wan, MX; Zhu, DB
1998-12-01
Source PublicationJOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY
ISSN0887-624X
Volume36Issue:17Pages:3013-3019
AbstractThe water-soluble conducting copolymer of poly(aniline-co-o-aminobenzenesulfonic acid) (PAOABSA) was synthesized directly from aniline and o-aminobenzenesulfonic acid and characterized by elemental analysis, FTIR, W-Vis, X-ray powder diffraction, and XPS. The room-temperature conductivity of the copolymer can be changed by controlling the molar fraction of the starting materials, and its maximum conductivity at room temperature can reach 3.4 S/cm, which is comparable with polyaniline (PANI) synthesized by the standard method and sulfonated polyaniline (SPAN) having a high degree of sulfonation reported by Wei et al. it was found that the room-temperature conductivity of the copolymer decreases with increase of the degree of sulfonation because of the introduction of the -SO3- group reducing the conjugation of the polymer chain. On the other hand, its solubility in 1.0M NaOH solution increases with increase of the degree of sulfonation due to the -SO3- group linking directly on the phenyl rings of the polymer chain. (C) 1998 John Wiley & Sons, Inc.
KeywordPolyaniline Water Soluble Degree Of Sulfonation Copolymerization
Indexed BySCI
Language英语
WOS IDWOS:000077290400002
PublisherJOHN WILEY & SONS INC
Citation statistics
Cited Times:49[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/74168
Collection中国科学院化学研究所
Corresponding AuthorWan, MX
AffiliationAcad Sinica, Inst Chem, Beijing 100080, Peoples R China
Recommended Citation
GB/T 7714
Fan, JH,Wan, MX,Zhu, DB. Synthesis and characterization of water-soluble conducting copolymer poly(aniline-co-o-aminobenzenesulfonic acid)[J]. JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY,1998,36(17):3013-3019.
APA Fan, JH,Wan, MX,&Zhu, DB.(1998).Synthesis and characterization of water-soluble conducting copolymer poly(aniline-co-o-aminobenzenesulfonic acid).JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY,36(17),3013-3019.
MLA Fan, JH,et al."Synthesis and characterization of water-soluble conducting copolymer poly(aniline-co-o-aminobenzenesulfonic acid)".JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY 36.17(1998):3013-3019.
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