ICCAS OpenIR
An ESR Study of Radical Intermediates in Electroreduction of Propargyl Alcohol
Kuang Yafei1; Li Guoxi1; Huang Shukun1; Lu Daohui2; Chen Dewen2
1997
Source PublicationACTA PHYSICO-CHIMICA SINICA
ISSN1000-6818
Volume13Issue:10Pages:954-956
AbstractElectrochemical-ESR technique (ex situ method) with spin traps phenyl text-butyl-nitrone (PBN) and 5,5-dimethyl-1-pyrroline-1-oxide (DMPO) has been applied to the detection of radical intermediates produced during electroreduction of propargyl alcohol (PA) at platinized platinum electrode in an acidified alcohol-aqua solution. Propargyl radical and H have been detected by PBN and DMPO, respectively. As a result of the discovery of these radicals, an evidence for a radical mechanism of the electroreduction of PA put forward by some authors might to obtained beyond all doubt.
KeywordPropargyl Alcohol Electroreduction Electrochemical-esr Spin Trapping
DOI10.3866/PKU.WHXB19971019
Indexed BySCI
Language英语
WOS IDWOS:000207602000019
PublisherPEKING UNIV PRESS
Citation statistics
Cited Times:1[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/74136
Collection中国科学院化学研究所
Corresponding AuthorKuang Yafei
Affiliation1.Hunan Univ, Coll Chem & Chem Engn, Changsha 410082, Hunan, Peoples R China
2.Acad Sinica, Inst Chem, Beijing 100080, Peoples R China
Recommended Citation
GB/T 7714
Kuang Yafei,Li Guoxi,Huang Shukun,et al. An ESR Study of Radical Intermediates in Electroreduction of Propargyl Alcohol[J]. ACTA PHYSICO-CHIMICA SINICA,1997,13(10):954-956.
APA Kuang Yafei,Li Guoxi,Huang Shukun,Lu Daohui,&Chen Dewen.(1997).An ESR Study of Radical Intermediates in Electroreduction of Propargyl Alcohol.ACTA PHYSICO-CHIMICA SINICA,13(10),954-956.
MLA Kuang Yafei,et al."An ESR Study of Radical Intermediates in Electroreduction of Propargyl Alcohol".ACTA PHYSICO-CHIMICA SINICA 13.10(1997):954-956.
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