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Study on the Thermodynamics of Axial Coordination Reaction of Iron-Phthalocyanine with Imidazoles
Gun Fuchun; Chen Dewen; Xu Guangshi
1997
Source PublicationACTA PHYSICO-CHIMICA SINICA
ISSN1000-6818
Volume13Issue:9Pages:838-842
AbstractThe thermodynamics of axial coordination reactions, of Fe-phthalocyanine with various ligands of imidazoles in DMF solution has been studied. The axial coordination number(n) and equilibrium constants (beta(n)) of the coordinating reaction were determined by spectral techniques. The steric and electrionic effects of the axial ligands were compared, The influence of temperature on the coordination reactions was discussed, The difference of axial coordinations of metallo-phthalocyanine and metallo-porphyrin with imidazoles was also analyzed.
KeywordMetallo-phthalocyanine Imidazole Thermodynamics Axial Coordination
DOI10.3866/PKU.WHXB19970913
Indexed BySCI
Language英语
WOS IDWOS:000207601900013
PublisherPEKING UNIV PRESS
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Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/74130
Collection中国科学院化学研究所
Corresponding AuthorGun Fuchun
AffiliationAcad Sinica, Inst Chem, Beijing 100080, Peoples R China
Recommended Citation
GB/T 7714
Gun Fuchun,Chen Dewen,Xu Guangshi. Study on the Thermodynamics of Axial Coordination Reaction of Iron-Phthalocyanine with Imidazoles[J]. ACTA PHYSICO-CHIMICA SINICA,1997,13(9):838-842.
APA Gun Fuchun,Chen Dewen,&Xu Guangshi.(1997).Study on the Thermodynamics of Axial Coordination Reaction of Iron-Phthalocyanine with Imidazoles.ACTA PHYSICO-CHIMICA SINICA,13(9),838-842.
MLA Gun Fuchun,et al."Study on the Thermodynamics of Axial Coordination Reaction of Iron-Phthalocyanine with Imidazoles".ACTA PHYSICO-CHIMICA SINICA 13.9(1997):838-842.
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