Het Photoelectron Spectroscopic Study of the Electronic Structure on B(OCH3)(3)

doi:10.3866/PKU.WHXB19960712

ICCAS OpenIR

	Het Photoelectron Spectroscopic Study of the Electronic Structure on B(OCH3)(3)
	Li Sheng 1; Li Ying 1; Wang Xiaohui 1; Ding Chuanfan 2; Chen Wenwu 2; Gao Yiqin 2; Wang Dianxun 1
	1996
Source Publication	ACTA PHYSICO-CHIMICA SINICA
ISSN	1000-6818
Volume	12 Issue:7 Pages:641-643
Abstract	Hel photoelectron sportrum of B(OCH3)(3) is presented in this rumen The assignment of the spectrum has been also done by an analysis of the intensity of the spectrum bands and the optimized MNDO molecular orbital calculation on B(OCH3)(3) molecule. The split showing a 1.08eV of the bands at the lowest two ionization potentials (IPs) was assigned to the Jahn-Teller split or the doubly degenerate oxygen lone-pair orbitals, And the splits showing 0.42eV and 0.380eV on the above-mentioned bands were considered as the result of spin-orbital interaction Therefore the tins PES study provides an exceedingly experimental example to testify the Jahn-Teller effect and the spin-orbital interaction splitting.
Keyword	Hel Photoelectron Spectroscopy (Pes) Trimethyl Borate Mndo Calculation
DOI	10.3866/PKU.WHXB19960712
Indexed By	SCI
Language	英语
WOS ID	WOS:000207600000012
Publisher	PEKING UNIV PRESS
Citation statistics
Document Type	期刊论文
Identifier	http://ir.iccas.ac.cn/handle/121111/74058
Collection	中国科学院化学研究所
Corresponding Author	Li Sheng
Affiliation	1.Acad Sinica, Inst Chem, State Key Lab Struct Chem Unstable & Stable Speci, Beijing 100080, Peoples R China 2.Acad Sinica, Inst Chem, State Key Lab Mol React Dynam, Beijing 100080, Peoples R China
Recommended Citation GB/T 7714	Li Sheng,Li Ying,Wang Xiaohui,et al. Het Photoelectron Spectroscopic Study of the Electronic Structure on B(OCH3)(3)[J]. ACTA PHYSICO-CHIMICA SINICA,1996,12(7):641-643.
APA	Li Sheng.,Li Ying.,Wang Xiaohui.,Ding Chuanfan.,Chen Wenwu.,...&Wang Dianxun.(1996).Het Photoelectron Spectroscopic Study of the Electronic Structure on B(OCH3)(3).ACTA PHYSICO-CHIMICA SINICA,12(7),641-643.
MLA	Li Sheng,et al."Het Photoelectron Spectroscopic Study of the Electronic Structure on B(OCH3)(3)".ACTA PHYSICO-CHIMICA SINICA 12.7(1996):641-643.

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