ICCAS OpenIR
Het Photoelectron Spectroscopic Study of the Electronic Structure on B(OCH3)(3)
Li Sheng1; Li Ying1; Wang Xiaohui1; Ding Chuanfan2; Chen Wenwu2; Gao Yiqin2; Wang Dianxun1
1996
Source PublicationACTA PHYSICO-CHIMICA SINICA
ISSN1000-6818
Volume12Issue:7Pages:641-643
AbstractHel photoelectron sportrum of B(OCH3)(3) is presented in this rumen The assignment of the spectrum has been also done by an analysis of the intensity of the spectrum bands and the optimized MNDO molecular orbital calculation on B(OCH3)(3) molecule. The split showing a 1.08eV of the bands at the lowest two ionization potentials (IPs) was assigned to the Jahn-Teller split or the doubly degenerate oxygen lone-pair orbitals, And the splits showing 0.42eV and 0.380eV on the above-mentioned bands were considered as the result of spin-orbital interaction Therefore the tins PES study provides an exceedingly experimental example to testify the Jahn-Teller effect and the spin-orbital interaction splitting.
KeywordHel Photoelectron Spectroscopy (Pes) Trimethyl Borate Mndo Calculation
DOI10.3866/PKU.WHXB19960712
Indexed BySCI
Language英语
WOS IDWOS:000207600000012
PublisherPEKING UNIV PRESS
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Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/74058
Collection中国科学院化学研究所
Corresponding AuthorLi Sheng
Affiliation1.Acad Sinica, Inst Chem, State Key Lab Struct Chem Unstable & Stable Speci, Beijing 100080, Peoples R China
2.Acad Sinica, Inst Chem, State Key Lab Mol React Dynam, Beijing 100080, Peoples R China
Recommended Citation
GB/T 7714
Li Sheng,Li Ying,Wang Xiaohui,et al. Het Photoelectron Spectroscopic Study of the Electronic Structure on B(OCH3)(3)[J]. ACTA PHYSICO-CHIMICA SINICA,1996,12(7):641-643.
APA Li Sheng.,Li Ying.,Wang Xiaohui.,Ding Chuanfan.,Chen Wenwu.,...&Wang Dianxun.(1996).Het Photoelectron Spectroscopic Study of the Electronic Structure on B(OCH3)(3).ACTA PHYSICO-CHIMICA SINICA,12(7),641-643.
MLA Li Sheng,et al."Het Photoelectron Spectroscopic Study of the Electronic Structure on B(OCH3)(3)".ACTA PHYSICO-CHIMICA SINICA 12.7(1996):641-643.
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