ICCAS OpenIR
The Measurement of the Ionization Potential and the Bond Energy Si(CH3)(2)Cl-2
Shen Liusi1; Qi Fei1; Zhang Yunwu1; Chen Wenwu2; Wang Zhaohui2; Ding Chuanfan2; Kong Fanao2
1995
Source PublicationACTA PHYSICO-CHIMICA SINICA
ISSN1000-6818
Volume11Issue:10Pages:870-872
AbstractThe vacuum ultraviolet photoionization spectrum of Si(CH3)(2)Cl-2 has been obtained with synchrotron radiation source. The adiabatic ionization potential of Si(CH3)(2)Cl-2 is 10.62 +/- 0.03eV (0.37eV lower than reported by PES), and the appearance potentials for Si(CH3)Cl-2(+), Si(CH3)(2)Cl+, SiCH3+ and SiCl+ are 11.25 +/- 0.03eV, 12.69 +/- 0.04eV, 15.1 +/- 0.1eV and 21.16eV +/- 0.1eV respectively. From these results, we estimate D(Si(CH3)Cl-2(+)-CH3)=0.63 +/- 0.03eV and D(Si(CH3)(2)Cl+-Cl))=2.07 +/- 0.04eV.
KeywordSi(Ch3)(2)Cl-2 Syrchrotron Radiation Photoionization Ionization Potential Chemical Bond Energy
DOI10.3866/PKU.WHXB19951002
Indexed BySCI
Language英语
WOS IDWOS:000207590900002
PublisherPEKING UNIV PRESS
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Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/74030
Collection中国科学院化学研究所
Corresponding AuthorShen Liusi
Affiliation1.Univ Sci & Technol China, Natl Lab Synchrotron Radiat, Hefei 230027, Peoples R China
2.Chinese Acad Sci, Inst Chem, State Key Lab Mol React Dynam, Beijing 100080, Peoples R China
Recommended Citation
GB/T 7714
Shen Liusi,Qi Fei,Zhang Yunwu,et al. The Measurement of the Ionization Potential and the Bond Energy Si(CH3)(2)Cl-2[J]. ACTA PHYSICO-CHIMICA SINICA,1995,11(10):870-872.
APA Shen Liusi.,Qi Fei.,Zhang Yunwu.,Chen Wenwu.,Wang Zhaohui.,...&Kong Fanao.(1995).The Measurement of the Ionization Potential and the Bond Energy Si(CH3)(2)Cl-2.ACTA PHYSICO-CHIMICA SINICA,11(10),870-872.
MLA Shen Liusi,et al."The Measurement of the Ionization Potential and the Bond Energy Si(CH3)(2)Cl-2".ACTA PHYSICO-CHIMICA SINICA 11.10(1995):870-872.
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