ICCAS OpenIR
MOLECULAR AND CRYSTAL STRUCTURE OF THE 2,4,7-TRINITROFLUORENONE-1,6-DI-(N-CARBAZOLYL) 2,4-HEXADIYNE CHARGE-TRANSFER COMPLEX
Yu Zhaolou; Zhu Naijue; Zhu Daoben
1987
Source PublicationACTA PHYSICO-CHIMICA SINICA
ISSN1000-6818
Volume3Issue:6Pages:663-667
AbstractThe molecular and crystal structure of the charge-transfer complex formed between 2,4,7-trinitrofluorenone (TNF) and 1,6-di-(N-carbazolyl-)2,4-hexadiyne (DCH) has been determined from three dimensional intensity measured on a R3m/E four circle diffractometer. The complex crystallizes with one done (DCH) and two acceptor (TNF) in a trielinic cell (P-1) of dimensions a = 7.190(1), b = 10.760(2), c = 15.438(3) angstrom and alpha = 88.34(2), beta = 88.86(2), gamma = 87.92(2)degrees. The structure was solved by direct method using SHELXTL program. The H atoms coordinates were caculated geometrically. The 1609 statistically significant reflections were refined by "blocked cascade" least squares to a final value of R=0.073. The separate schematic drawings of the donor and acceptor molecules with the bond lengths and angles are shown in Fig.Ia and Ib. The acceptor (TNF) and denor (DCH) molecules lie in bc-planes with average distance of 2.40 angstrom between the molecules.
DOI10.3866/PKU.WHXB19870620
Indexed BySCI
Language英语
WOS IDWOS:000207569600020
PublisherPEKING UNIV PRESS
Citation statistics
Cited Times:1[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/74000
Collection中国科学院化学研究所
Corresponding AuthorYu Zhaolou
AffiliationAcad Sinica, Inst Chem, Beijing 100080, Peoples R China
Recommended Citation
GB/T 7714
Yu Zhaolou,Zhu Naijue,Zhu Daoben. MOLECULAR AND CRYSTAL STRUCTURE OF THE 2,4,7-TRINITROFLUORENONE-1,6-DI-(N-CARBAZOLYL) 2,4-HEXADIYNE CHARGE-TRANSFER COMPLEX[J]. ACTA PHYSICO-CHIMICA SINICA,1987,3(6):663-667.
APA Yu Zhaolou,Zhu Naijue,&Zhu Daoben.(1987).MOLECULAR AND CRYSTAL STRUCTURE OF THE 2,4,7-TRINITROFLUORENONE-1,6-DI-(N-CARBAZOLYL) 2,4-HEXADIYNE CHARGE-TRANSFER COMPLEX.ACTA PHYSICO-CHIMICA SINICA,3(6),663-667.
MLA Yu Zhaolou,et al."MOLECULAR AND CRYSTAL STRUCTURE OF THE 2,4,7-TRINITROFLUORENONE-1,6-DI-(N-CARBAZOLYL) 2,4-HEXADIYNE CHARGE-TRANSFER COMPLEX".ACTA PHYSICO-CHIMICA SINICA 3.6(1987):663-667.
Files in This Item:
There are no files associated with this item.
Related Services
Recommend this item
Bookmark
Usage statistics
Export to Endnote
Google Scholar
Similar articles in Google Scholar
[Yu Zhaolou]'s Articles
[Zhu Naijue]'s Articles
[Zhu Daoben]'s Articles
Baidu academic
Similar articles in Baidu academic
[Yu Zhaolou]'s Articles
[Zhu Naijue]'s Articles
[Zhu Daoben]'s Articles
Bing Scholar
Similar articles in Bing Scholar
[Yu Zhaolou]'s Articles
[Zhu Naijue]'s Articles
[Zhu Daoben]'s Articles
Terms of Use
No data!
Social Bookmark/Share
All comments (0)
No comment.
 

Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.